Atkins' Physical Chemistry 11e
Atkins' Physical Chemistry 11e
11th Edition
ISBN: 9780192575135
Author: Peter Atkins; Julio de Paula; James Keeler
Publisher: Oxford University Press Academic UK
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Chapter 19, Problem 19B.1BE
Interpretation Introduction

Interpretation:

Applying Langmuir isotherm, the value of Vmon has to be calculated.

Concept Introduction:

Assumptions of Langmuir isotherm:

  • Beyond monolayer coverage adsorption does not proceed.
  • In a surface all the sites are equivalent.
  • A molecule can be adsorbed only at a vacant site.
  • Due to no interactions between adsorbed molecules, the probability of adsorption is independent of the occupation of neighboring sites.

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