Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 19, Problem 19.50AP
Interpretation Introduction

(a)

Interpretation:

The complete series of reactions by giving the major organic product is to be stated.

Concept introduction:

The chemical reaction in which the carbonyl functional group is converted to an alkane is known as Wolff-Kishner reduction. This reaction takes place in the presence of NH2NH2 and a strong base like sodium hydroxide followed by the heating.

Interpretation Introduction

(b)

Interpretation:

The way by which the major organic product, 1ethyl4methoxybenzene is prepared from hydroquinone monomethyl ether or pmethoxyphenol is to be stated.

Concept introduction:

The chemical reaction in which an unsaturated halide or triflate reacts with an alkene in the presence of a base like pyridine and a palladium catalyst is known as Heck reaction. The product of the Heck reaction is a substituted alkene.

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Explain the following behaviours :(i) Alcohols are more soluble in water than the hydrocarbons of comparable molecular masses.(ii) Ortho-nitrophenol is more acidic than ortho-methoxyphenol.
Answer ALL parts of this question. (a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b) Provide a reaction scheme for the preparation of nitrous acid. (c) Draw the structure of the product formed exclusively when nitrous acid reacts with Z. (d) Give a curly arrow mechanism for the preparation of the yellow azo-dye from the reaction of Z with benzenediazonium chloride.
(a) Draw the structure of a compound of molecular formula C6H10 that reacts with H2 in the presence of Pd-C but does not react with H2 in the presence of Lindlar catalyst. (b) Draw the structure of a compound of molecular formula C6H10 that reacts with H2 when either catalyst is present.

Chapter 19 Solutions

Organic Chemistry Study Guide and Solutions

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