The use of amine synthesis for the conversion of allybromide to allylamine is to be shown. Concept introduction: The Gabriel synthesis is used for the preparation of primary amines . It is also called Gabriel phthalimide synthesis. In this synthesis N − alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 1

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Students have asked these similar questions

The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)

6. The reaction between aniline and nitrous acid at low temperature yields A) an N-nitroso amine B) a diazonium salt C) a nitrile D) an amine nitrite salt 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acid

Reductive amination of carbonyl compounds produces the same kinds of products as does the reaction of amines and alkyl halides True or False

Answer 2

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 3

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 4

Question

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

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Answer 5

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 6

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 7

Chapter 19, Problem 19.48SP

(a)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of allybromide to allylamine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of ethylbenzene to p-ethylaniline is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 3-phenylheptan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The use of amine synthesis for the conversion of 1-bromo-3-phenylheptane to 4-phenyloctan-1-amine is to be shown.

Concept introduction:

The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis N− alkylated potassium or sodium salt of phthalimide is hydrolysed with alkalies. Such alkaline hydrolysis results in corresponding primary amine.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains the Gabriel synthesis, which is used for the preparation of primary amines.

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Chapter 19 Solutions