Chemistry: Atoms First
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 19, Problem 19.122QP
Interpretation Introduction

Interpretation:

The rate of the given reactions from graphs has to be ranked.  The ΔH values for each reaction and which reaction is exothermic and which reaction is endothermic has to be determined.

Concept introduction:

Exothermic reaction: Exothermic reaction is said to be a chemical reaction in which energy will released in the form of heat.  In general this reaction has to be represented as follows.

 Reactants  Products + Energy

Endothermic reaction: Endothermic reaction is said to be a chemical reaction in which energy will consumed in the form of heat.  In general this reaction has to be represented as follows.

 Reactants + Energy Products 

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Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.(i) Cl2 (g) + Pt (s) à 2Cl (g) + Pt (s) Ea = 1550 kJ ∆H = – 950 kJ(ii) Cl (g)+ CO (g) + Pt (s) à ClCO (g) + Pt (s) Ea = 2240 kJ ∆H = 575 kJ(iii) Cl (g) + ClCO (g) à Cl2CO (g) Ea = 2350 kJ ∆H = – 825 kJ e. Which reaction intermediate would be considered a catalyst (if any) and why?f. If you were to add 2700kJ of activation energy to the reaction, would you be able to make thereaction reverse itself (i.e. have the products become reactants)? Justify your answer.g. If you were to added a positive catalyst to step (iii) what would the end result be? Justify yourprediction. h. Your friend is looking at your graph and states that she believes that step (ii) is the ratedetermining step. Do you agree with her? Justify your reasoning.
The data below were collected for the following reaction at 35° C: 2(CH3)3 CSOH(g) → (CH3)3CS(O)SC(CH3)3 (g) Time (min) [(CH3)3 CSOH] (mol · L−¹) 0.0 1.554 10.8 0.661 19.1 0.343 37.0 0.083 59.5 0.014 75.1 0.004 Part C From the slope of the appropriate plot, determine the value of the rate constant at this temperature. VG ΑΣΦ Submit Request Answer ? 5-1

Chapter 19 Solutions

Chemistry: Atoms First

Ch. 19.4 - The gas-phase reaction of nitric oxide with...Ch. 19.5 - Calculate the rate constant for the first-order...Ch. 19.5 - Prob. 19.7WECh. 19.5 - The reaction 2A B is second order in A with a rate...Ch. 19.5 - Prob. 7PPBCh. 19.5 - Prob. 19.5.4SRCh. 19.7 - Prob. 19.11WECh. 19.7 - Prob. 11PPACh. 19.7 - Prob. 11PPBCh. 19.7 - Consider the gas-phase reaction of nitric oxide...Ch. 19.7 - Prob. 12PPBCh. 19 - The rate of a reaction in which the reactant...Ch. 19 - The rate of a reaction in which the reactant...Ch. 19 - The rate of a reaction in which the reactant...Ch. 19 - Increasing the temperature of a reaction increases...Ch. 19 - Define activation energy. What role does...Ch. 19 - Sketch a potential energy versus reaction progress...Ch. 19 - The reaction H + H2 H2 + H has been studied for...Ch. 19 - What is meant by the rate of a chemical reaction?...Ch. 19 - Distinguish between average rate and instantaneous...Ch. 19 - What are the advantages of measuring the initial...Ch. 19 - Prob. 19.7QPCh. 19 - Consider the reaction N2(g)+3H2(g)2NH3(g) Suppose...Ch. 19 - Prob. 19.9QPCh. 19 - Prob. 19.10QPCh. 19 - Prob. 19.11QPCh. 19 - Prob. 19.12QPCh. 19 - Prob. 19.13QPCh. 19 - What are the units for the rate constants of...Ch. 19 - Consider the zeroth-order reaction: A product....Ch. 19 - Prob. 19.16QPCh. 19 - Prob. 19.17QPCh. 19 - Prob. 19.18QPCh. 19 - Prob. 19.19QPCh. 19 - Prob. 19.20QPCh. 19 - Prob. 19.21QPCh. 19 - Prob. 19.22QPCh. 19 - Prob. 19.23QPCh. 19 - Prob. 19.24QPCh. 19 - Prob. 19.25QPCh. 19 - Prob. 19.26QPCh. 19 - Prob. 19.27QPCh. 19 - Prob. 19.28QPCh. 19 - Prob. 19.29QPCh. 19 - Prob. 19.30QPCh. 19 - Prob. 19.31QPCh. 19 - The rate constant for the second-order reaction...Ch. 19 - Prob. 19.33QPCh. 19 - Consider the first-order reaction X Y shown here,...Ch. 19 - Prob. 19.35QPCh. 19 - Consider the first-order reaction A B in which A...Ch. 19 - Prob. 19.37QPCh. 19 - Prob. 19.38QPCh. 19 - Prob. 19.39QPCh. 19 - Prob. 19.40QPCh. 19 - Prob. 19.41QPCh. 19 - Prob. 19.42QPCh. 19 - Prob. 19.43QPCh. 19 - Prob. 19.44QPCh. 19 - Prob. 19.45QPCh. 19 - The rate at which tree crickets chirp is 2.0 102...Ch. 19 - Prob. 19.47QPCh. 19 - The activation energy for the denaturation of a...Ch. 19 - Variation of the rate constant with temperature...Ch. 19 - Prob. 19.50QPCh. 19 - Prob. 19.51QPCh. 19 - Prob. 19.52QPCh. 19 - Prob. 19.53QPCh. 19 - What is an elementary step? What is the...Ch. 19 - Prob. 19.55QPCh. 19 - Determine the molecularity, and write the rate law...Ch. 19 - What is the rate-determining step of a reaction?...Ch. 19 - Prob. 19.58QPCh. 19 - Prob. 19.59QPCh. 19 - Classify each of the following elementary steps as...Ch. 19 - Prob. 19.61QPCh. 19 - Prob. 19.62QPCh. 19 - Prob. 19.63QPCh. 19 - Prob. 19.64QPCh. 19 - Prob. 19.65QPCh. 19 - What are the characteristics of a catalyst?Ch. 19 - Prob. 19.67QPCh. 19 - Prob. 19.68QPCh. 19 - The concentrations of enzymes in cells are usually...Ch. 19 - Prob. 19.70QPCh. 19 - Prob. 19.71QPCh. 19 - Prob. 19.72QPCh. 19 - Prob. 19.73QPCh. 19 - Prob. 19.74QPCh. 19 - Prob. 19.75QPCh. 19 - In a certain industrial process involving a...Ch. 19 - Prob. 19.77QPCh. 19 - Prob. 19.78QPCh. 19 - Explain why most metals used in catalysis arc...Ch. 19 - Prob. 19.80QPCh. 19 - Prob. 19.81QPCh. 19 - Prob. 19.82QPCh. 19 - Prob. 19.83QPCh. 19 - Prob. 19.84QPCh. 19 - The bromination of acetone is acid-catalyzed. The...Ch. 19 - The decomposition of N2O to N2 and O2 is a...Ch. 19 - Prob. 19.87QPCh. 19 - Prob. 19.88QPCh. 19 - The integrated rate law for the zeroth-order...Ch. 19 - Prob. 19.90QPCh. 19 - Prob. 19.91QPCh. 19 - Prob. 19.92QPCh. 19 - The reaction of G2 with E2 to form 2EG is...Ch. 19 - Prob. 19.94QPCh. 19 - Prob. 19.95QPCh. 19 - Prob. 19.96QPCh. 19 - Strictly speaking, the rate law derived for the...Ch. 19 - Prob. 19.98QPCh. 19 - The decomposition of dinitrogen pentoxide has been...Ch. 19 - Prob. 19.100QPCh. 19 - Prob. 19.101QPCh. 19 - Prob. 19.102QPCh. 19 - To prevent brain damage, a standard procedure is...Ch. 19 - Prob. 19.104QPCh. 19 - Prob. 19.105QPCh. 19 - Prob. 19.106QPCh. 19 - Prob. 19.107QPCh. 19 - Prob. 19.108QPCh. 19 - Prob. 19.109QPCh. 19 - Prob. 19.110QPCh. 19 - (a) What can you deduce about the activation...Ch. 19 - Prob. 19.112QPCh. 19 - Prob. 19.113QPCh. 19 - Prob. 19.114QPCh. 19 - Prob. 19.115QPCh. 19 - Prob. 19.116QPCh. 19 - Prob. 19.117QPCh. 19 - Prob. 19.118QPCh. 19 - Prob. 19.119QPCh. 19 - Prob. 19.120QPCh. 19 - Prob. 19.121QPCh. 19 - Prob. 19.122QPCh. 19 - Consider the following potential energy profile...Ch. 19 - Prob. 19.124QPCh. 19 - Prob. 19.125QPCh. 19 - Prob. 19.126QPCh. 19 - Prob. 19.127QPCh. 19 - Prob. 19.128QPCh. 19 - The following expression shows the dependence of...Ch. 19 - Prob. 19.130QPCh. 19 - The rale constant for the gaseous reaction H2(g) +...Ch. 19 - Prob. 19.132QPCh. 19 - Prob. 19.133QPCh. 19 - At a certain elevated temperature, ammonia...Ch. 19 - Prob. 19.135QPCh. 19 - The rate of a reaction was followed by the...Ch. 19 - Prob. 19.137QPCh. 19 - Prob. 19.138QP
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