Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 18, Problem 90IE
The following data were collected for the destruction of O3by
H (O3 + H (O2 + OH) at very low concentrations:
Trial | [O3] (M) | [H] (M) | Initial rate (M/s) |
1 | 5.17×10-33 | 3.22×10-26 | 1.88×10-14 |
2 | 2.59×10-33 | 3.25×10-26 | 9.44×10-15 |
3 | 5.19×10-33 | 6.46×10-26 | 3.77×10-14 |
(a) Write the rate law for the reaction.
(b) Calculate the rate constant.
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The following data were collected for the destruction of O3
by H (O, + H – 02 + OH) at very low concentrations:
Trial (0] (M)
[H] (M)
Initial Rate (M/s)
1.
5.17 x 10-33
3.22 x 10-26 1.88 x 10-14
2.59 x 10-33 3.25 x 10-26 9.44 x 10-15
5.19 x 10-33 6.46 × 10-26 3.77 x 10-14
(a) Write the rate law for the reaction.
(b) Calculate the rate constant.
3.
5. The following data was obtained from the reaction:
NH4+ (aq) + NO2 (aq) → N2(g) + 2H2O(1)
Initial Concentration (mol/L)
Initial rate (mol/Ls)
NO2-
NH4+
0.010
0.020
5.4 x 10-7
0.020
0.020
10.8 x 10-7
0.040
0.020
21.6 x 10-7
0.020
0.0202
10.8 x 10-7
0.020
0.0404
21.6 x 10-7
0.020
0.0606
32.4 x 10-7
(a) Determine the rate law.
(b) Calculate the rate constant.
(c) Calculate the initial rate, if [NO2] = 0.1 M and [NH4*] = 0.1 M
The following data were measured for the reaction of nitric oxide with hydrogen:
6.
2 NOg)2 H2g) -> N2(g) + 2 H20(g)
Experiment
Number
Initial Rate (M/s)
H2 (M)
INO] (M)
1.23 x 103
1
0.10
0.10
2
0.10
0.20
2.46 x 10
4.92 x 10
0.20
0.10
(a) Determine the rate law for this reaction. (b) Calculate the rate constant. (c) Calculate the rate when
[NO] 0.050 Mand [H2] = 0.150 M
Chapter 18 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 18.1 - Carbon monoxide, CO, is isoelectronic to N2. a....Ch. 18.1 - The energy-level diagram in Figure 9.36 shows that...Ch. 18.1 - A compound composed of 2.1 29.8%N, and 68.1%O has...Ch. 18.1 -
9.114 Sulfur tetrafluoride (SR4) reacts slowly...Ch. 18 - Prob. 1DECh. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - Prob. 3ECh. 18 - Prob. 4ECh. 18 - You have a gas at 25C confined to a cylinder with...
Ch. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - Prob. 8ECh. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 -
Gallium melts just above room temperature...Ch. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - Do the reactions involved in ozone depletion...Ch. 18 - Which of the following reactions in the...Ch. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - 18.30 The first stage in corrosion of iron upon...Ch. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - (a) With respect to absorption of radiant energy,...Ch. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Prob. 44ECh. 18 - List the common products formed when an organic...Ch. 18 - Prob. 46ECh. 18 - The organic anion is found in most detergents....Ch. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63AECh. 18 - Prob. 64AECh. 18 - Prob. 65AECh. 18 - Prob. 66AECh. 18 - Prob. 67AECh. 18 - Prob. 68AECh. 18 - (a) What is the difference between a CFC and an...Ch. 18 - Prob. 70AECh. 18 - Prob. 71AECh. 18 - Prob. 72AECh. 18 - Prob. 73AECh. 18 - Prob. 74AECh. 18 - Prob. 75AECh. 18 - Prob. 76AECh. 18 - Prob. 77AECh. 18 - Prob. 78AECh. 18 - Prob. 79AECh. 18 - Prob. 80IECh. 18 - Prob. 81IECh. 18 - Prob. 82IECh. 18 - Prob. 83IECh. 18 - Prob. 84IECh. 18 - Prob. 85IECh. 18 - Prob. 86IECh. 18 - The standard enthalpies of formation of...Ch. 18 - The main reason that distillation is a costly...Ch. 18 - Prob. 89IECh. 18 - The following data were collected for the...Ch. 18 - Prob. 91IECh. 18 - Prob. 92IECh. 18 - Prob. 93IECh. 18 - Prob. 94IECh. 18 - Prob. 95IE
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