Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 18, Problem 46E

Write balanced chemical equations for the reaction of the following acid anhydrides with water:

(a) SO3

(b) N2O3

(c) Cl2O7

(d) P4O10

(e) NO2

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Write balanced chemical equations for the reaction of the following acid anhydrides with water: (a) SO3     (b) N2O3
(a) Hydrogen peroxide (HOOH) has a pKa of 11.6, making it roughly 10,000 times as strong an acid as water(pKa = 15.7). Explain why H2O2 is a stronger acid than H2O.(b) In contrast to part (a), peroxyacetic acid (pKa = 8.2) is a much weaker acid than acetic acid (pKa = 4.74). Explainwhy peroxyacetic acid is a weaker acid than acetic acid.(c) Peroxyacetic acid (bp = 105 °C) has a lower boiling point than acetic acid (bp = 118 °C), even though peroxyaceticacid has a higher molecular weight. Explain why peroxyacetic acid is more volatile than acetic acid
(a) What is the hybridization of the nitrogen in each of the following compounds? (b) How does hybridization affect the availability of the lone pair and the basicity of each compound?

Chapter 18 Solutions

Chemistry by OpenStax (2015-05-04)

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