Connect  One Semester Access Card for General, Organic, & Biological Chemistry
Connect One Semester Access Card for General, Organic, & Biological Chemistry
4th Edition
ISBN: 9781260194654
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
Question
Book Icon
Chapter 18, Problem 31P
Interpretation Introduction

(a)

Interpretation:

From the given compounds from E to H, a compound containing a primary amine and a primary amide needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 .Amines are classified as 10, 20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Amide- is an organic compound contains the group of C(O)NH2 , formed from ammonia by replacing one or more H atoms.

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

Expert Solution
Check Mark

Answer to Problem 31P

Structure H.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Furthermore,

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

In the below structure, bond that is indicated in red color is the single CN bond in the amide group which makes it as a 10 amide. Bond that is indicated in blue color is the single CN bond in the amine group which is responsible for the 10 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 31P , additional homework tip  1

Hence, structure H is a compound that contains a 10 amine and a 10 amide.

Interpretation Introduction

(b)

Interpretation:

From the given compounds from E to H, a compound containing a primary amine and a secondary amide needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 . Amines are classified as 10, 20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Amide- is an organic compound contains the group of C(O)NH2 , formed from ammonia by replacing one or more H atoms.

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

Expert Solution
Check Mark

Answer to Problem 31P

Structure F.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Furthermore,

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

In the below structure, bonds that are indicated in red color are the two CN bonds in the amide group which makes it as a 20 amide. Bond that is indicated in blue color is the single CN bond in the amine group which is responsible for the 10 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 31P , additional homework tip  2

Hence, structure F is a compound that contains a 10 amine and a 20 amide.

Interpretation Introduction

(c)

Interpretation:

From the given compounds from E to H, a compound containing a secondary amine and a tertiary amide needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 . Amines are classified as 10, 20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Amide- is an organic compound contains the group of C(O)NH2 , formed from ammonia by replacing one or more H atoms.

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

Expert Solution
Check Mark

Answer to Problem 31P

Structure E.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Furthermore,

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

In the below structure, bonds that are indicated in red color are the three CN bonds in the amide group which makes it as a 30 amide. Bonds that are indicated in blue color are the two CN bonds in the amine group which is responsible for the 20 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 31P , additional homework tip  3

Hence, structure E is a compound that contains a 20 amine and a 30 amide.

Interpretation Introduction

(d)

Interpretation:

From the given compounds from E to H, a compound containing a tertiary amine and a tertiary amide needs to be identified.

Concept Introduction:

Amine − is an organic N compounds formed by replacing one or more H atoms of NH3 . Amines are classified as 10, 20 or 30 by the number of alkyl groups bonded to the N atom.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Amide- is an organic compound contains the group of C(O)NH2 , formed from ammonia by replacing one or more H atoms.

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

Expert Solution
Check Mark

Answer to Problem 31P

Structure G.

Explanation of Solution

Amines are formed by replacing one or more hydrogen atoms of ammonia with alkyl groups.

  10 amines - Consist only one CN bond.

  20 amines- Consist two CN bonds.

  30 amines- Consist three CN bonds.

Furthermore,

  10 amides - Consist only one CN bond

  20 amides- Consist two CN bonds

  30 amides- Consist three CN bonds

In the below structure, bonds that are indicated in red color are the three CN bonds in the amide group which makes it as a 30 amide. Bonds that are indicated in blue color are the two CN bonds in the amine group which is responsible for the 20 amine structure.

Connect  One Semester Access Card for General, Organic, & Biological Chemistry, Chapter 18, Problem 31P , additional homework tip  4

Hence, structure G is a compound that contains a 30 amine and a 30 amide.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
Classify each of the molecules below. 1° amine 1° amine 1° amine 2° amine 2° amine 3° amine 3° amine not an amine at all not an amine at all 2° amine 3° amine not an amine at all
Classify each of the molecules below. x NH₂ 1° amine 2° amine 3° amine not an amine at all NH₂ 1° amine 2° amine 3° amine not an amine at all NH₂ 1° amine 2° amine 3° amine not an amine at all
r Talking: Question 14.b of 25 Classify and describe the properties of the following nitrogen containing compound. Provide a systematic name for this structure. 2- N,N- 4- 1- tert- tri di sec- H N H. I N- N,N,N- n- prop but hex Submit +

Chapter 18 Solutions

Connect One Semester Access Card for General, Organic, & Biological Chemistry

Ch. 18.5 - Prob. 18.8PCh. 18.5 - Naloxone is a drug used to treat overdoses of...Ch. 18.6 - Prob. 18.4PPCh. 18.6 - Prob. 18.10PCh. 18.6 - Prob. 18.11PCh. 18.6 - Name each ammonium salt. a. ( CH3 NH3)+Cl b. [( CH...Ch. 18.6 - Prob. 18.6PPCh. 18.6 - Prob. 18.12PCh. 18.7 - Prob. 18.13PCh. 18.7 - Prob. 18.14PCh. 18.8 - Prob. 18.15PCh. 18.8 - Prob. 18.16PCh. 18.8 - Prob. 18.17PCh. 18.8 - Prob. 18.18PCh. 18.9 - Prob. 18.19PCh. 18.9 - Prob. 18.20PCh. 18.9 - Prob. 18.21PCh. 18.10 - Prob. 18.22PCh. 18 - Prob. 23PCh. 18 - Prob. 24PCh. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - Prob. 31PCh. 18 - Prob. 32PCh. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b. c....Ch. 18 - Give an acceptable name for each amine. a. CH3(...Ch. 18 - Prob. 37PCh. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - Prob. 40PCh. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Prob. 44PCh. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Draw the hydrogen-bonding interactions that occur...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Which compound has the higher water solubility:...Ch. 18 - Prob. 51PCh. 18 - Prob. 52PCh. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Prob. 55PCh. 18 - Prob. 56PCh. 18 - What type of nitrogen heterocycle occurs in both...Ch. 18 - Only one of the N atoms in nicotine has a trigonal...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Why are aqueous solutions of an alkaloid slightly...Ch. 18 - Prob. 62PCh. 18 - Prob. 63PCh. 18 - Explain why patients with Parkinson’s disease...Ch. 18 - Prob. 65PCh. 18 - Prob. 66PCh. 18 - Prob. 67PCh. 18 - Prob. 68PCh. 18 - Locate the atoms of 2-phenylethylamine in the...Ch. 18 - Locate the atoms of 2-phenylethylamine in the...Ch. 18 - Give an example of an antihistamine. Explain how...Ch. 18 - Give an example of an anti-ulcer drug, and explain...Ch. 18 - Prob. 73PCh. 18 - Prob. 74PCh. 18 - Prob. 75PCh. 18 - Prob. 76PCh. 18 - Prob. 77PCh. 18 - Prob. 78PCh. 18 - Prob. 79PCh. 18 - Why do some antihistamines cause drowsiness while...Ch. 18 - Prob. 81PCh. 18 - Prob. 82PCh. 18 - Compare the structures of morphine and heroin....Ch. 18 - Prob. 84CP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry In Focus
Chemistry
ISBN:9781337399692
Author:Tro, Nivaldo J.
Publisher:Cengage Learning,