Chemical Principles in the Laboratory
11th Edition
ISBN: 9781305264434
Author: Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher: Brooks Cole
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Chapter 18, Problem 2ASA
Interpretation Introduction
Interpretation:
The reagents used and the corresponding reaction for the preparation of nitrogen
Concept introduction:
The elements that have low conductivity (thermal and electrical) and brittle in nature are known as non-metals. Compounds containing nonmetallic atoms are generally bonded by a covalent bond. The nonmetallic compounds are prepared by simple reactions in the laboratory.
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1A)Given the following value, tell whether the starting material or product is
favored at equilibrium. Keq = 6 A. Starting material favored B. Product favored
2B) Given the following value, tell whether the starting material or product is
favored at equilibrium. DG = 5 kcal/mol A. Starting material favored B. Product favored
Consider this reaction:
Br
CH3OH
Br-Br
H3CO
The mechanism proceeds through a first cationic intermediate, intermediate 1. Nucleophilic attack leads to intermediate 2, which goes on to form the final product. In cases that involve a
negatively charged nucleophile, the attack of the nucleophile leads directly to the product.
H.
Br
+ CH;OH
Br
Intermediate 2
(product)
Intermediate 1
In a similar fashion, draw intermediate 1 and intermediate 2 (final product) for the following reaction.
OH
+ Br2
+ HBr
Br
racemic mixture
For the acid-base reaction of sodium bicarbonate, NaHCO3, with hydrochloric acid, HCl, select all of the products of the reaction
For the acid-base reaction of sodium bicarbonate, NaHCO3, with hydrochloric acid, HCl, select all of the products of the reaction
NaCl
NaOH
OH-
Na2CO3
H2O
CO2
CO32-
H+
Chapter 18 Solutions
Chemical Principles in the Laboratory
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