Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Question
Chapter 18, Problem 18.5QAP
Interpretation Introduction
(a)
Interpretation:
The ratio and comparison of intensities of the anti-Stokes and Stokes line for
Concept introduction:
The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.
Interpretation Introduction
(b)
Interpretation:
The ratio and comparison of intensities of the anti-Stokes and Stokes line for
Concept introduction:
The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.
Interpretation Introduction
(b)
Interpretation:
The ratio and comparison of intensities of the anti-Stokes and Stokes line for
Concept introduction:
The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.
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The vibrational temperature of a molecule prepared in a
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b.
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(i)
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Estimate the vibrational partition function at 298 K.
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Estimate the fundamental vibration wave number for this molecule.
h = 6.626 x 10-3ª J s
k= 1.38 x 1023 J K'
c = 2.998 x 10® m s''
(c)
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mixing.
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J (1 → 2): 6714.44 MHz
J (2 → 3): 10068.90 MHz
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