Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Chemistry: An Atoms-Focused Approach
Ch. 17 - Prob. 17.1VPCh. 17 - Prob. 17.2VPCh. 17 - Prob. 17.3VPCh. 17 - Prob. 17.4VPCh. 17 - Prob. 17.5VPCh. 17 - Prob. 17.6VPCh. 17 - Prob. 17.7VPCh. 17 - Prob. 17.8VPCh. 17 - Prob. 17.9VPCh. 17 - Prob. 17.10VP
Ch. 17 - Prob. 17.11QACh. 17 - Prob. 17.12QACh. 17 - Prob. 17.13QACh. 17 - Prob. 17.14QACh. 17 - Prob. 17.15QACh. 17 - Prob. 17.16QACh. 17 - Prob. 17.17QACh. 17 - Prob. 17.18QACh. 17 - Prob. 17.19QACh. 17 - Prob. 17.20QACh. 17 - Prob. 17.21QACh. 17 - Prob. 17.22QACh. 17 - Prob. 17.23QACh. 17 - Prob. 17.24QACh. 17 - Prob. 17.25QACh. 17 - Prob. 17.26QACh. 17 - Prob. 17.27QACh. 17 - Prob. 17.28QACh. 17 - Prob. 17.29QACh. 17 - Prob. 17.30QACh. 17 - Prob. 17.31QACh. 17 - Prob. 17.32QACh. 17 - Prob. 17.33QACh. 17 - Prob. 17.34QACh. 17 - Prob. 17.35QACh. 17 - Prob. 17.36QACh. 17 - Prob. 17.37QACh. 17 - Prob. 17.38QACh. 17 - Prob. 17.39QACh. 17 - Prob. 17.40QACh. 17 - Prob. 17.41QACh. 17 - Prob. 17.42QACh. 17 - Prob. 17.43QACh. 17 - Prob. 17.44QACh. 17 - Prob. 17.45QACh. 17 - Prob. 17.46QACh. 17 - Prob. 17.47QACh. 17 - Prob. 17.48QACh. 17 - Prob. 17.49QACh. 17 - Prob. 17.50QACh. 17 - Prob. 17.51QACh. 17 - Prob. 17.52QACh. 17 - Prob. 17.53QACh. 17 - Prob. 17.54QACh. 17 - Prob. 17.55QACh. 17 - Prob. 17.56QACh. 17 - Prob. 17.57QACh. 17 - Prob. 17.58QACh. 17 - Prob. 17.59QACh. 17 - Prob. 17.60QACh. 17 - Prob. 17.61QACh. 17 - Prob. 17.62QACh. 17 - Prob. 17.63QACh. 17 - Prob. 17.64QACh. 17 - Prob. 17.65QACh. 17 - Prob. 17.66QACh. 17 - Prob. 17.67QACh. 17 - Prob. 17.68QACh. 17 - Prob. 17.69QACh. 17 - Prob. 17.70QACh. 17 - Prob. 17.71QACh. 17 - Prob. 17.72QACh. 17 - Prob. 17.73QACh. 17 - Prob. 17.74QACh. 17 - Prob. 17.75QACh. 17 - Prob. 17.76QACh. 17 - Prob. 17.77QACh. 17 - Prob. 17.78QACh. 17 - Prob. 17.79QACh. 17 - Prob. 17.80QACh. 17 - Prob. 17.81QACh. 17 - Prob. 17.82QACh. 17 - Prob. 17.83QACh. 17 - Prob. 17.84QACh. 17 - Prob. 17.85QACh. 17 - Prob. 17.86QACh. 17 - Prob. 17.87QACh. 17 - Prob. 17.88QACh. 17 - Prob. 17.89QACh. 17 - Prob. 17.90QACh. 17 - Prob. 17.91QACh. 17 - Prob. 17.92QACh. 17 - Prob. 17.93QACh. 17 - Prob. 17.94QACh. 17 - Prob. 17.95QACh. 17 - Prob. 17.96QACh. 17 - Prob. 17.97QACh. 17 - Prob. 17.98QACh. 17 - Prob. 17.99QACh. 17 - Prob. 17.100QACh. 17 - Prob. 17.101QACh. 17 - Prob. 17.102QA
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- Calculate G for the following reactions and state whether each reaction is spontaneous under standard conditions at 298 K. (a) 2Na(s) + H2SO4() Na2SO4(s) + H2(g) (b) Cu(s) + H2SO4() CuSO4(s) + H2(g)arrow_forwardCalculate E°, G°, and K at 25°C for the reaction 3Mn2+(aq)+2MnO4(aq)+2H2O5MnO2(s)+4H+(aq)arrow_forwardCalculate E°, G°, and K at 25°C for the reaction 3MnO4(aq)+4H+(aq)+Cl2(g)2Mn2+(aq)+2ClO3(aq)+2H2Oarrow_forward
- Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forwardHydrazine, N2H4, can be used as the reducing agent in a fuel cell. N2H4(aq) + O2(aq) N2(g) + 2 H2O () (a) If rG for the reaction is 598 kJ, calculate the valueof E expected for the reaction. (b) Suppose the equation is written with all coefficients doubled. Determine rG and E for this new reaction.arrow_forwardCalculate the equilibrium constant at 25 C for each of the following reactions from the value G given. (a) I2(s)+Cl2(l)2ICl(g)G=10.88kJ (b) H2(g)+I2(s)2HI(g)G=3.4kJ (c) CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)G=39kJ (d) 2SO2(g)+O2(g)2SO3(g)G=141.82kJ (e) CS2(g)CS2(l)G=1.88kJarrow_forward
- For each of the reactions, calculate E from the table of standard potentials, and state whether the reaction is spontaneous as written or spontaneous in the reverse direction under standard conditions. (a) Cu2+(aq)+Ni(s)Cu(s)+Ni2+(aq) (b) 2Ag(s)+Cl2(g)2AgCl(s) (c) Cl2(g)+2I(aq)2Cl(aq)+I2(s)arrow_forwardTable 17-1 lists common half-reactions along with the standard reduction potential associated with each half-reaction. These standard reduction potentials are all relative to some standard. What is the standard (zero point)? lf is positive for a half-reaction, what does it mean? If is negative for a half-reaction, what does it mean? Which species in Table 17-1 is most easily reduced? Least easily reduced? The reverse of the half-reactions in Table 17-1 are the oxidation half-reactions. How are standard oxidation potentials determined? In Table 17-1, which species is the best reducing agent? The worst reducing agent? To determine the standard cell potential for a redox reaction, the standard reduction potential is added to the standard oxidation potential. What must be true about this sum if the cell is to be spontaneous (produce a galvanic cell)? Standard reduction and oxidation potentials are intensive. What does this mean? Summarize how line notation is used to describe galvanic cells.arrow_forwardAnother type of battery is the alkaline zinc-mercury cell, in which the cell reaction is Zn(s) + HgO(s) Hg() + ZnO(s) E = + 1.35 V (a) What is the standard free energy change for this reaction? (b) The standard free energy change in a voltaic cell is the maximum electrical energy that the cell can produce. If the reaction in a zinc-mercury cell consumes 1.00 g mercury oxide, what is the standard free energy change? (c) For how many hours could a mercury cell produce a 10-mA current if the limiting reactant is 3.50 g mercury oxide?arrow_forward
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