Explanation The molecular orbital diagram of cyclooctatetraene is represented as shown below. Figure 1 It is seen from the above diagram that a total of 8 π electrons are involved in the formation of continuous ring of cyclooctatetraene

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ISBN: 9780134645704

Author: WADE AND SIMEK

Publisher: PEARSON

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Question

Chapter 16.4, Problem 16.5P

Interpretation Introduction

Interpretation: An explanation corresponding to the stable or unstable configuration using MO diagram of cyclooctatetraene is to be stated.

Concept introduction: The diagrams that involve the linear combination of atomic orbitals are known as molecular orbital diagrams. These diagrams represent the bonding as well as non bonding electrons.

To determine: An explanation corresponding to the stable or unstable configuration using MO diagram of cyclooctatetraene.

Expert Solution & Answer

Chapter 16 Solutions

ORGANIC CHEMISTRY

Ch. 16.2 - Prob. 16.1P Ch. 16.2 - Prob. 16.2P Ch. 16.2 - a. Draw the resonance forms of benzene,...Ch. 16.2 - Show the product of the Diels-Alder dimerization...Ch. 16.4 - Prob. 16.5P Ch. 16.6 - Make a model of cyclooctatetraene in the tub...Ch. 16.6 - Prob. 16.7P Ch. 16.6 - Prob. 16.8P Ch. 16.7 - Prob. 16.9P Ch. 16.8A - a. Draw the molecular orbitals for the...

Ch. 16.8A - Repeat Problem16-10 for the cyclopentadienyl ions....Ch. 16.8C - Explain why each compound or ion should be...Ch. 16.8C - The following hydrocarbon has an unusually large...Ch. 16.8C - Prob. 16.14P Ch. 16.8C - Prob. 16.15P Ch. 16.9B - Prob. 16.16P Ch. 16.9C - Show which of the nitrogen atoms in purine are...Ch. 16.9C - The proton NMR spectrum of 2-pyridone gives the...Ch. 16.9D - Prob. 16.19P Ch. 16.9D - Prob. 16.20P Ch. 16.10 - Prob. 16.21P Ch. 16.12 - Ciprofloxacin is a member of the fluoroquinolone...Ch. 16.13 - Draw and name all the chlorinated benzenes having...Ch. 16.13 - Name the following compounds:Ch. 16.15 - The UV spectrum of 1-phenylprop-2-en-1-ol shows an...Ch. 16 - Prob. 16.26SP Ch. 16 - Name the following compounds:Ch. 16 - Draw and name all the methyl, dimethyl, and...Ch. 16 - Four pairs of compounds are shown. In each pair,...Ch. 16 - One of the following hydrocarbons is much more...Ch. 16 - In Kekuls time cyclohexane was unknown, and there...Ch. 16 - Prob. 16.32SP Ch. 16 - Azulene is a deep-blue hydrocarbon with resonance...Ch. 16 - Prob. 16.34SP Ch. 16 - Prob. 16.35SP Ch. 16 - Prob. 16.36SP Ch. 16 - Prob. 16.37SP Ch. 16 - Prob. 16.38SP Ch. 16 - Prob. 16.39SP Ch. 16 - Biphenyl has the following structure. a. Is...Ch. 16 - Anions of hydrocarbons are rare, and dianions of...Ch. 16 - How would you convert the following compounds to...Ch. 16 - Prob. 16.43SP Ch. 16 - Prob. 16.44SP Ch. 16 - A student found an old bottle labeled thymol on...Ch. 16 - Prob. 16.46SP Ch. 16 - Prob. 16.47SP Ch. 16 - Prob. 16.48SP Ch. 16 - The proton NMR chemical shifts of the hydrogens in...Ch. 16 - Prob. 16.50SP Ch. 16 - NMR has been used to probe many molecular...

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