EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 16.3, Problem 5CC

Draw an energy diagram showing the relative energy levels of the M O s for 1,3,5,7-octatetraene and identify the H O M O and L U M O for both the ground state and the excited state.

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C5H10O2 H Determine H and C Spectra for the compund
In the electron paramagnetic resonance spectrum ofthe propyl radical, C3H5, the hyperfine splitting constant is1.45 mT for coupl ing to the protons on the terminal carbonatoms and 0.406 mT for coupl ing to the protons attached tothe central carbon atom. Taking 0= 2.25 mT, use the McConnellequation to estimate the unpaired electron density on eachcarbon atom.
Assign the hydrogens from C4H10O to this spectra.
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