ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 1.6, Problem 6LTS
Interpretation Introduction
Interpretation: The number of carbon atoms present in diazepam should be identified and all the hydrogen atoms needs to be filled in the structure.
Concept Introduction: A method used to represent molecular structures of compounds is said to be bond line notation. In this notation, a line depicts a bond between two atoms and are drawn in a zigzag format. Atoms other than carbon and hydrogens are specifically depicted in this notation. It is assumed that carbon atoms are bonded to enough hydrogen atoms that are required to complete the octet.
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Functional Groups
FUNCTIONAL GROUPS IN ORGANIC CHEMISTRY
FUNCTIONAL GROUPS ARE GROUPS OF ATOMS IN ORGANIC MOLECULES THAT ARE RESPONSIBLE FOR THE CHARACTERISTIC CHEMICAL REACTIONS OF THOSE MOLECULES.
IN THE GENERAL FORMULAE SHOWN BELOW FOR EACH FUNCTIONAL GROUP, 'R' REPRESENTS THE REST OF THE MOLECULE, AND X REPRESENTS ANY HALOGEN ATOM.
HALOGEN HETEROATOMICS CARBONYL COMPOUNDS
HYDROCARBONS
SIMPLE OXYGEN HETEROATOMICS
NITROGEN-BASED SULFUR-BASED
AROMATIC
R-OH
0-R₂
R-X
ALKANE
ALKENE
ALKYNE
EPOXIDE
Noming one
egethane
Noming ene
egethene
Noming ye
ALCOHOL
Naming-of
egethanol
ETHER
Naming-ory ane
eg. methoxyethane
Naming ene oxide
egethene oxide
HALOALKANE
Naming: holo
eg. chloroethane
eg ethyne
ÅR
(PNP)
-Å-X
OR₂
ALDEHYDE
Naming al
eg ethanal
KETONE
Naming: one
eg propanone
CARBOXYLIC ACID
Naming oic acid
eg, ethanoic acid
ACID ANHYDRIDE
Noming oic anhydride
eg. ethanoic anhydride
ESTER
Naming late
eg. ethyl ethanoate
AMIDE
Naming: amide
eg. ethanamide
ACYL HALIDE
Naming ay halide
eg…
The red colour in cabbage is due to the presence of a range of anthocyanins such as cyanidin. Draw both the molecular structure for cyanidin (showing all carbon and hydrogen atoms) and the line structure (using lines and not showing carbon atoms or hydrogen atoms that are attached to carbon atoms).
TRUE OR FALSE
All atoms play a role in the physicochemical and pharmacologic properties of a molecule.
Sophistication and advancement in technology are the main driving forces of drug development.
Organic medicinal chemistry is the study of matter, specifically, all carbon-containing compounds.
A functional group will always have the same physicochemical properties, regardless of its neighboring atoms in a molecular structure.
Addition of a single methyl group in a drug molecule may result to changes in physical, chemical, pharmacokinetic, and pharmacologic properties.
Steric effects occur when bulky and large functional groups are near each other in a molecular structure.
Molecules that are highly capable of hydrogen bonding tend to be more soluble in nonpolar solvents.
Chapter 1 Solutions
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
Ch. 1.2 - Prob. 1LTSCh. 1.2 - Prob. 2ATSCh. 1.2 - Prob. 2LTSCh. 1.3 - Prob. 3LTSCh. 1.3 - Prob. 4PTSCh. 1.3 - Prob. 5PTSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 7PTSCh. 1.4 - Prob. 8PTSCh. 1.4 - Prob. 9ATS
Ch. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 10PTSCh. 1.5 - Prob. 11ATSCh. 1.5 - Prob. 12ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 14ATSCh. 1.7 - Prob. 7LTSCh. 1.7 - Prob. 17ATSCh. 1.10 - Prob. 18CCCh. 1.10 - Prob. 20CCCh. 1.10 - Prob. 8LTSCh. 1.10 - Prob. 21PTSCh. 1.10 - Nemotin is a compound that was first isolated from...Ch. 1.10 - Prob. 23CCCh. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 24PTSCh. 1.11 - Prob. 25PTSCh. 1.11 - Prob. 26PTSCh. 1.11 - Prob. 27ATSCh. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 29ATSCh. 1.13 - Prob. 11LTSCh. 1.13 - Prob. 31ATSCh. 1 - Prob. 32PPCh. 1 - Prob. 33PPCh. 1 - Prob. 34PPCh. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Nicotine is an addictive substance found in...Ch. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 59PPCh. 1 - Prob. 63ASPCh. 1 - Prob. 64ASPCh. 1 - Prob. 66ASPCh. 1 - Prob. 69ASPCh. 1 - Prob. 71ASPCh. 1 - Prob. 72ASPCh. 1 - Prob. 75IP
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