Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 15, Problem 88QRT
Interpretation Introduction
Interpretation:
The relative concentrations of aniline and anilinium chloride required to prepare a buffer with
Concept Introduction:
The buffer is a solution that resists any change in pH on addition of
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A chemistry graduate student is given 100. mL of a 0.90M trimethylamine ((CH3)N) solution. Trimethylamine is a weak base with K₁=7.4 × 104.
f (CH3)2NHCl should the student dissolve in the (CH3)2N solution to turn it into a buffer with pH = 10.66?
mass of
You may assume that the volume of the solution doesn't change when the (CH3)2NHC1 is dissolved in it. Be sure your answer has a unit symbol, and round it
to 2 significant digits.
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A chemistry graduate student is given 250. mL of a 1.40M ammonia (NH3) solution. Ammonia is a weak base with K-1.8x10
should the student dissolve in the NH3 solution to turn it into a buffer with pH = 9.17?
What mass of NH, Br
You may assume that the volume of the solution doesn't change when the NH4Br is dissolved in it. Be sure your answer has a unit symbol, and round it to 2
significant digits.
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Chapter 15 Solutions
Chemistry: The Molecular Science
Ch. 15.1 - Predict whether 1.0 L of each solution is a...Ch. 15.1 - Calculate the pH of blood containing 0.0020-M...Ch. 15.1 - Prob. 15.2ECh. 15.1 -
Calculate the ratio of [] to [] in blood at a...Ch. 15.1 - Use the data in Table 15.1 to select a conjugate...Ch. 15.1 -
Calculate the mole ratio of sodium acetate and...Ch. 15.1 - Calculate the pH of these buffers.
Ch. 15.1 - If an abnormally high CO2 concentration is present...Ch. 15.1 - Calculate the minimum mass (g) of KOH that would...Ch. 15.2 - For the titration of 50.0 mL of 0.100-M HCl with...
Ch. 15.2 - Draw the titration curve for the titration of 50.0...Ch. 15.2 - Use the Ka expression and value for acetic acid to...Ch. 15.2 - Explain why the curve for the titration of acetic...Ch. 15.4 - Write the Ksp expression for each of these...Ch. 15.4 - The Ksp of AgBr at 100 C is 5 1010. Calculate the...Ch. 15.4 - A saturated solution of silver oxalate. Ag2C2O4....Ch. 15.4 - Prob. 15.9CECh. 15.5 - Consider 0.0010-M solutions of these sparingly...Ch. 15.5 - Prob. 15.11PSPCh. 15.5 - Calculate the solubility of PbCl2 in (a) pure...Ch. 15.5 - Prob. 15.13PSPCh. 15.6 - (a) Determine whether AgCl precipitates from a...Ch. 15.6 - Prob. 15.15PSPCh. 15 - Prob. 1SPCh. 15 - Choose a weak-acid/weak-base conjugate pair from...Ch. 15 - Prob. 4SPCh. 15 - Define the term buffer capacity.Ch. 15 - What is the difference between the end point and...Ch. 15 - What are the characteristics of a good acid-base...Ch. 15 - A strong acid is titrated with a strong base, such...Ch. 15 - Repeat the description for Question 4, but use a...Ch. 15 - Use Le Chatelier’s principle to explain why PbCl2...Ch. 15 - Describe what a complex ion is and give an...Ch. 15 - Define the term “amphoteric”.
Ch. 15 - Distinguish between the ion product (Q) expression...Ch. 15 - Describe at least two ways that the solubility of...Ch. 15 - Briefly describe how a buffer solution can control...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Many natural processes can be studied in the...Ch. 15 - Which of these combinations is the best to buffer...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Calculate the mass of sodium acetate, NaCH3COO,...Ch. 15 - Calculate the mass in grams of ammonium chloride,...Ch. 15 - A buffer solution can be made from benzoic acid,...Ch. 15 - A buffer solution is prepared from 5.15 g NH4NO3...Ch. 15 - You dissolve 0.425 g NaOH in 2.00 L of a solution...Ch. 15 - A buffer solution is prepared by adding 0.125 mol...Ch. 15 - If added to 1 L of 0.20-M acetic acid, CH3COOH,...Ch. 15 - If added to 1 L of 0.20-M NaOH, which of these...Ch. 15 - Calculate the pH change when 10.0 mL of 0.100-M...Ch. 15 - Prob. 29QRTCh. 15 - Prob. 30QRTCh. 15 - Prob. 31QRTCh. 15 - The titration curves for two acids with the same...Ch. 15 - Explain why it is that the weaker the acid being...Ch. 15 - Prob. 34QRTCh. 15 - Consider all acid-base indicators discussed in...Ch. 15 - Which of the acid-base indicators discussed in...Ch. 15 - It required 22.6 mL of 0.0140-M Ba(OH)2 solution...Ch. 15 - It took 12.4 mL of 0.205-M H2SO4 solution to...Ch. 15 - Vitamin C is a monoprotic acid. To analyze a...Ch. 15 - An acid-base titration was used to find the...Ch. 15 - Calculate the volume of 0.150-M HCl required to...Ch. 15 - Calculate the volume of 0.225-M NaOH required to...Ch. 15 - Prob. 43QRTCh. 15 - Prob. 44QRTCh. 15 - Prob. 45QRTCh. 15 - Explain why rain with a pH of 6.7 is not...Ch. 15 - Identify two oxides that are key producers of acid...Ch. 15 - Prob. 48QRTCh. 15 - Prob. 49QRTCh. 15 - Prob. 50QRTCh. 15 - Prob. 51QRTCh. 15 - A saturated solution of silver arsenate, Ag3AsO4,...Ch. 15 - Prob. 53QRTCh. 15 - Prob. 54QRTCh. 15 - Prob. 55QRTCh. 15 - Prob. 56QRTCh. 15 - Prob. 57QRTCh. 15 - Prob. 58QRTCh. 15 - Prob. 59QRTCh. 15 - Prob. 60QRTCh. 15 - Prob. 61QRTCh. 15 - Prob. 62QRTCh. 15 - Prob. 63QRTCh. 15 - Prob. 64QRTCh. 15 - Predict what effect each would have on this...Ch. 15 - Prob. 66QRTCh. 15 - Prob. 67QRTCh. 15 - The solubility of Mg(OH)2 in water is...Ch. 15 - Prob. 69QRTCh. 15 - Prob. 70QRTCh. 15 - Prob. 71QRTCh. 15 - Prob. 72QRTCh. 15 - Write the chemical equation for the formation of...Ch. 15 - Prob. 74QRTCh. 15 - Prob. 75QRTCh. 15 - Prob. 76QRTCh. 15 - Prob. 77QRTCh. 15 - Prob. 78QRTCh. 15 - Prob. 79QRTCh. 15 - Prob. 80QRTCh. 15 - Prob. 81QRTCh. 15 - Solid sodium fluoride is slowly added to an...Ch. 15 - Prob. 83QRTCh. 15 - Prob. 84QRTCh. 15 - A buffer solution was prepared by adding 4.95 g...Ch. 15 - Prob. 86QRTCh. 15 - Prob. 87QRTCh. 15 - Prob. 88QRTCh. 15 - Prob. 89QRTCh. 15 - Which of these buffers involving a weak acid HA...Ch. 15 - Prob. 91QRTCh. 15 - Prob. 92QRTCh. 15 - When 40.00 mL of a weak monoprotic acid solution...Ch. 15 - Each of the solutions in the table has the same...Ch. 15 - Prob. 95QRTCh. 15 - Prob. 97QRTCh. 15 - The average normal concentration of Ca2+ in urine...Ch. 15 - Explain why even though an aqueous acetic acid...Ch. 15 - Prob. 100QRTCh. 15 - Prob. 101QRTCh. 15 - Prob. 102QRTCh. 15 - Prob. 103QRTCh. 15 - Prob. 104QRTCh. 15 - Apatite, Ca5(PO4)3OH, is the mineral in teeth.
On...Ch. 15 - Calculate the maximum concentration of Mg2+...Ch. 15 - Prob. 107QRTCh. 15 - Prob. 108QRTCh. 15 - The grid has six lettered boxes, each of which...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Prob. 112QRTCh. 15 - Prob. 113QRTCh. 15 - Prob. 114QRTCh. 15 - Prob. 115QRTCh. 15 - You want to prepare a pH 4.50 buffer using sodium...Ch. 15 - Prob. 117QRTCh. 15 - Prob. 118QRTCh. 15 - Prob. 119QRTCh. 15 - Prob. 120QRTCh. 15 - Prob. 121QRTCh. 15 - Prob. 122QRTCh. 15 - You are given four different aqueous solutions and...Ch. 15 - Prob. 124QRTCh. 15 - Prob. 126QRTCh. 15 - Prob. 15.ACPCh. 15 - Prob. 15.BCP
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- You have a 18 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 8.35. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 6.03. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 18 mL sample.arrow_forwardYou have a 18 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 7.82. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 5.66. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 18 mL sample. Tip: your answer should have two significant digits! Only the mantissa (the digits to the right of the decimal) are significant when you raise a decimal number to a power. CH,—C−O−CH,—CH,—*N—CH, Acetylcholine CH 3 acetycholine in original sample: CH3 H₂O CH3 HO–CH,—CH,—*N–CH, + CH, Choline CH3 CH, T Acetate O + H+ nmolarrow_forwardYou have a 16 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 7.66. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 5.52. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 16 mL sample. Acetylcholine CH₂ acetycholine in original sample: CH,—C−O−CH,—CH,AN-CH, HO–CH,—CH,*N–CH, + CHy H₂O I CH3 CH3 Choline CH₂ CH,-GO + H Acetate nmolarrow_forward
- A student was required to prepare 250.0 mL of a cyanoacetic acid/sodium cyanoacetate buffer in which the concentration of the weak acid component was 0.06 M and the concentration of the conjugate base was 0.028 M. The student was supplied with 0.512 M cyanoacetic acid and 1.0M NaOH to perform this task. What volume (in mL) of the acid would the student need to prepare this buffer solution? Hint: assume that all of the conjugate base comes directly from the reaction of NaOH with the weak acid (in other words, there is negligible dissociation of the weak acid). Please enter answers with 2 decimal places.arrow_forwardOne of the factors that can affect the pH of a buffered solution is the molar ratio of the conjugate base and weak acid. Which of the following statement is correct? "If the concentration of the conjugate base is higher than the weak acid, the pH will be less than the pKa." "If the concentration of the conjugate base is less than the weak acid, the pH will be less than the pKa." "If the concentration of the conjugate base is higher than the weak acid, the net change of the pH is going to the acidic side (lower pH)" "If the concentration of the conjugate base is less than the weak acid, the net change of the pH is going to the basic side (higher pH)"arrow_forwardYou have a 15 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 8.06. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 5.91. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 15 mL sample. O= CH3 Acetylcholine H₂O CH,—C−O−CH,—CH,—*N-CH, → HO−CH,—CH,—*N–CH, + CH,—C−O + H* CH3 CH 3 Choline CH3 Acetatearrow_forward
- 3.) A chemistry graduate student is given 300.mL of a 0.50M pyridine C5H5N solution. Pyridine is a weak base with Kb = 1.7x10^−9. What mass of C5H5NHBr should the student dissolve in the C5H5N solution to turn it into a buffer with pH =5.54? You may assume that the volume of the solution doesn't change when the C5H5NHBr is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 significant digits.arrow_forwardA chemistry graduate student is given 450. mL of a 0.50M trimethylamine ((CH3)N) solution. Trimethylamine is a weak base with K₁=7.4 × 10¯ª. What mass of (CH3)NHBr should the student dissolve in the (CH3)2N solution to turn it into a buffer with pH = 11.20? You may assume that the volume of the solution doesn't change when the (CH3) NHBr is dissolved in it. Be sure your answer has a 3 unit symbol, and round it to 2 significant digits. ? 10: 000arrow_forwardYou have a 12 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 8.14. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 6.55. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 12 mL sample. Acetycholine in original sample:________ nmolarrow_forward
- You have a 20 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 8.17. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 6.70. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 20 mL sample. -Å-—•- CH,—C−O−CH,—CH,—*N–CH, Acetylcholine CH₂ acetycholine in original sample: CH₂ H₂O CH₂ I HO–CH,—CH,—*N–CH, + CH Choline CH₂ CHO Acetate H* nmolarrow_forwardYou have a 11 mL sample of acetylcholine (a neurotransmitter) with an unknown concentration and a pH of 8.22. You incubate this sample with the enzyme acetylcholinesterase to convert all of the acetylcholine to choline and acetic acid. The acetic acid dissociates to yield acetate and hydrogen ions. At the end of the incubation period, you measure the pH again and find that it has decreased to 6.62. Assuming there was no buffer in the assay mixture, determine the number of nanomoles of acetylcholine in the original 11 mL sample. CH,—C−O−CH,—CH,—*N-CH, Acetylcholine CH3 acetycholine in original sample: I CH₂ H₂O CH₂ HO–CH,—CH,—*N–CH, + CH,-C−O + H* CH₂-8-0 Choline | CH3 Acetate nmolarrow_forwardA chemistry graduate student is given 300. mL of a 1.40M ammonia (NH, solution. Ammonia is a weak base with K, =1.8 × 10 °. What mass of NH, Br -5 should the student dissolve in the NH, solution to turn it into a buffer with pH =9.81? You may assume that the volume of the solution doesn't change when the NH,Br is dissolved in it. Be sure your answer has a unit symbol, and round it to 2 4 significant digits. x10 Explanation Check Accessibili 2022 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center MacBook Proarrow_forward
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Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY