
(a)
The work done by engine during the 4 steps and the net work done.
(a)

Answer to Problem 86P
The work done by engine during the 4 steps are 692 J,0 J,−506 J ,0 J and the net work done is 186 J.
Explanation of Solution
Write the expression for work done during process A.
WA=nRTln(VfVi)
Here, T is the temperature, WA is the work done, Vi is the volume, Vf is the final volume and R is the gas constant.
B and D are isochoric processes. Therefore, work done is zero.
Write the expression for work done during process C.
WC=nRTln(VfVi)
Here, T is the temperature, WC is the work done, Vi is the volume, Vf is the final volume and R is the gas constant.
Conclusion:
For the process A,
Substitute 373 K for T,0.020 m3 for Vi, 0.025 m3 for Vf, 1.00 mol for n and 8.314 Jmol−1K−1 for R to get WA.
WA=(1.00 mol)(8.314 Jmol−1K−1)(373 K)ln(0.025 m30.020 m3)=692 J
For the process C,
Substitute 273 K for T, 0.025 m3 for Vi, 0.020 m3 for Vf, 1.00 mol for n and 8.314 Jmol−1K−1 for R to get WC.
WC=(1.00 mol)(8.314 Jmol−1K−1)(273 K)ln(0.020 m30.025 m3)=−506 J
The net work done is,
Wnet=(692 J)+(0 J)+(−506 J)+(0 J)=186 J
Therefore, work done by engine during the 4 steps are 692 J,0 J,−506 J ,0 J and the net work done is 186 J.
(b)
The efficiency of the engine.
(b)

Answer to Problem 86P
The efficiency of the engine is 0.0670.
Explanation of Solution
Write the expression for efficiency of the engine.
e=WnetQin
Here, e is the efficiency and Qin is input heat.
Write the expression for input heat.
Qin=52nRΔT+WA
Here, ΔU is the change in internal energy and ΔT is the change intemperature.
Therefore, the input heat is,
Qin=52(1.00 mol)(8.314 Jmol−1K−1)(373 K−273 K)+(692 J)=2792 J
Conclusion:
Substitute 186 J for Wnet and 2792 J for Qin to get e.
e=186 J2792 J=0.0670
Therefore, efficiency of the engine is 0.0670.
(c)
The ratio of efficiency of reversible engine and the given engine.
(c)

Answer to Problem 86P
The ratio of efficiency of reversible engine and the given engine is 4.00.
Explanation of Solution
Write the expression for the efficiency of reversible engine.
er=1−TCTH
Here, TC is the temperature of cold reservoir and TH is the temperature of the hot reservoir.
Conclusion:
Substitute 273 K for TC and 373 K for TH to get er.
er=1−273 K373 K=0.268
The ratio is given by,
ere=0.2680.0670=4.00
The ratio of efficiency of reversible engine and the given engine is 4.00.
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