Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 15, Problem 80AE
For the equilibrium
PH3BCI3 (s) ⇌ PH3 (g) + BCI3 (g)
Kp = 0.052 at 60 o C.
- Calculate Kc.
- After 3.00 g of solid PH3BCI3 is added to a closed 1.500-L vessel at 60 o C, the vessel is charged with 0.0500 g of BCI3 (g). What is the equilibrium concentration of PH3 ?
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Chapter 15 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 15.2 - Prob. 15.1.1PECh. 15.2 - Prob. 15.1.2PECh. 15.2 - Prob. 15.2.1PECh. 15.2 - Prob. 15.2.2PECh. 15.3 - Prob. 15.3.1PECh. 15.3 - Practice Exercise 2 For the reaction H2 (g) + I2...Ch. 15.3 - Prob. 15.4.1PECh. 15.3 - Prob. 15.4.2PECh. 15.4 - Prob. 15.5.1PECh. 15.4 - Prob. 15.5.2PE
Ch. 15.4 - Practice Exercise 1
If 8.0 g of NH4HS(s)...Ch. 15.4 - Prob. 15.6.2PECh. 15.5 - Practice Exercise 1
A mixture of gaseous sulfur...Ch. 15.5 - Prob. 15.7.2PECh. 15.5 - Practice Exercise 1 In Section 15.1, we discussed...Ch. 15.5 - Practice Exercise 2
The gaseous compound BrCl...Ch. 15.6 - Prob. 15.9.1PECh. 15.6 - Practice Exercise 2 At 1000 k, the value of Kp for...Ch. 15.6 - Prob. 15.10.1PECh. 15.6 - Prob. 15.10.2PECh. 15.6 - Practice Exercise 1 For the equilibrium Br2(g) +...Ch. 15.6 - Prob. 15.11.2PECh. 15.7 - Practice Exercise 1 For the reaction 4 NH3(g) + 5...Ch. 15.7 - Prob. 15.12.2PECh. 15 - Prob. 1DECh. 15 - Based on the following energy profile, predict...Ch. 15 - 15.2 The following diagrams represent a...Ch. 15 - Prob. 3ECh. 15 - Prob. 4ECh. 15 - Prob. 5ECh. 15 - 15.6 Ethene (C2H4) reacts with healogens (X2) by...Ch. 15 - When lead(IV) oxide is heated above 300 O C, it...Ch. 15 - Prob. 8ECh. 15 - The reactin A2(g) + B(g) + A(g) + AB(g) has an...Ch. 15 - Prob. 10ECh. 15 - Prob. 11ECh. 15 - The following graph represents the yield of the...Ch. 15 - Suppose that the gas-phase reactions A B and B A...Ch. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - Write the expression for KC for the following...Ch. 15 - When the following reaction come to equilibrium,...Ch. 15 - Prob. 18ECh. 15 - Prob. 19ECh. 15 - Prob. 20ECh. 15 - If Kc = 0.042 for PC13(g) + C12 (g) PC15 (g) at...Ch. 15 - Prob. 22ECh. 15 - 15.23 The equilibrium constant for the...Ch. 15 - Prob. 24ECh. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - The following equilibria were attained at 823 K:...Ch. 15 - Consider the equilibrium N2(g) + O2(g) + Br2(g) 2...Ch. 15 - Mercury(I) oxide decomposes into elemental mercury...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - Prob. 33ECh. 15 - Phosphorus trichloride gas and chlorine gas react...Ch. 15 - A mixture of 0.10 mol of NO, 0.050 mol of H2, and...Ch. 15 - Prob. 36ECh. 15 - A mixture of 0.2000 mol of CO2, 0.1000 mol of H2,...Ch. 15 - 15.38 A flask is charged with 1.500 atm of N2O4(g)...Ch. 15 - Prob. 39ECh. 15 - Prob. 40ECh. 15 - a. If QC KC, in which direction will a reaction...Ch. 15 - Prob. 42ECh. 15 - At 100 OC , the equilibrium constant for the...Ch. 15 - 15.44 As shown in Table 15.2, KP for the...Ch. 15 - At 100 C, K = 0.078 for the reaction SO2Cl2 (g) ...Ch. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - At 800 k, the equilibrium constant for I2 (g) ...Ch. 15 - Prob. 50ECh. 15 - At 2000 OC, the equilibrium constant for the...Ch. 15 - For the equilibrium Br2 (g) + Cl2 (g) 2BrCl(g) At...Ch. 15 - At 373 k, Kp = 0.416 for the equilibrium 2NOBr (g)...Ch. 15 - At 218 oC, KC= 1.2 X 10-4 for the equilibrium NH4...Ch. 15 - Prob. 55ECh. 15 - At 80 oC, K =1.87 X 10-3 for the reaction PH3 BCl3...Ch. 15 - Prob. 57ECh. 15 - Prob. 58ECh. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - Consider the following equilibrium for which H<0...Ch. 15 - Prob. 62ECh. 15 - 15.63 How do the following changes affect the...Ch. 15 - Prob. 64ECh. 15 - Consider the following equilibrium between oxides...Ch. 15 - Prob. 66ECh. 15 - Ozone, O3, decomposes to molecular oxygen in the...Ch. 15 - Prob. 68ECh. 15 - Prob. 69ECh. 15 - 15.70 True or false: When the temperature of an...Ch. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - 15.73 A mixture of CH4 and H2O is passed over a...Ch. 15 - Prob. 74AECh. 15 - Prob. 75AECh. 15 - Prob. 76AECh. 15 - Prob. 77AECh. 15 - Prob. 78AECh. 15 - Prob. 79AECh. 15 - For the equilibrium PH3BCI3 (s) PH3 (g) + BCI3...Ch. 15 - Prob. 81AECh. 15 - Prob. 82AECh. 15 - Prob. 83AECh. 15 - At 900 o C, Kc = 0.0108 for the reaction CaCO3(g) ...Ch. 15 - Prob. 85AECh. 15 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 15 - Prob. 87AECh. 15 - Le Chatelier noted that many industrial processes...Ch. 15 - Prob. 89AECh. 15 - Prob. 90AECh. 15 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 15 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 15 - Prob. 93AECh. 15 - Prob. 94AECh. 15 - Prob. 95IECh. 15 - The following equilibria were measured at 823 K:...Ch. 15 - Prob. 97IECh. 15 - Prob. 98IECh. 15 - At 800 K, the equilibrium constant for the...Ch. 15 - Prob. 100IECh. 15 - Prob. 101IECh. 15 - Prob. 102IE
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- Nonearrow_forwardUnshared, or lone, electron pairs play an important role in determining the chemical and physical properties of organic compounds. Thus, it is important to know which atoms carry unshared pairs. Use the structural formulas below to determine the number of unshared pairs at each designated atom. Be sure your answers are consistent with the formal charges on the formulas. CH. H₂ fo H2 H The number of unshared pairs at atom a is The number of unshared pairs at atom b is The number of unshared pairs at atom c is HC HC HC CH The number of unshared pairs at atom a is The number of unshared pairs at atom b is The number of unshared pairs at atom c isarrow_forwardDraw curved arrows for the following reaction step. Arrow-pushing Instructions CH3 CH3 H H-O-H +/ H3C-C+ H3C-C-0: CH3 CH3 Harrow_forward
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