EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Chapter 15, Problem 6E
Interpretation Introduction
Interpretation:
The partial pressure and number of moles of hydrogen are to be predicted.
Concept introduction:
According to the Dalton’s law of gases the relation the partial pressure of a component is equal to the product of total pressure of the gas mixture and mole fraction of that component.
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Gases produced by a chemical reaction can easily be collected over water. To determine the pressure of the dry gas, the vapor pressure of
he water at that temperature must be subtracted from the total pressure.
1) Consider the following reaction:
Mg(s) + 2 HCl(aq) →→→ MgCl₂(aq) + H₂(g)
The total pressure of gas collected over water 680.0 mmHg and the temperature is 25.5°C What is the pressure of hydrogen gas formed in mmHg?
mmHg
Pressure =
A student experimentally determines the gas law constant, R, by reacting a small piece of
magnesium with excess hydrochloric acid and then collecting the hydrogen gas over water
in a eudiometer. Based on experimentally collected data, the student calculates R to equal
L'atm
0.0832
mol·K
L'atm
Ideal gas law constant from literature: 0.08206
mol·K
(a) Determine the percent error for the student's R-value.
Percent error =|1.389
(b) For the statements below, identify the possible source(s) of error for this student's trial.
The student uses the barometric pressure for the lab to calculate R.
The student does not equilibrate the water levels within the eudiometer and the
beaker at the end of the reaction. The water level in the eudiometer is 1-inch
above the water level in the beaker.
The student does not clean the zinc metal with sand paper.
The student notices a large air bubble in the eudiometer after collecting the
hydrogen gas, but does not dislodge it.
Sulfur dioxide reacts with oxygen in the presence of plati-
num to give sulfur trioxide:
2 SO2(g) + O2(g) → 2 SO3(g)
Suppose that at one stage in the reaction, 26.0 mol SO2,
83.0 mol O2, and 17.0 mol SO3 are present in the reaction
vessel at a total pressure of 0.950 atm. Calculate the mole
fraction of SO3 and its partial pressure.
Chapter 15 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
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