Interpretation:
The volume of a hexagonal unit cell has to be derived.
Concept Introduction:
From a vector analysis, we know that volume of a geometric system can be alternatively written as
Explanation of Solution
First we have to derive the volume of a triclinic unit cell. Then we can take it as the reference to derive the volume of a hexagonal unit cell.
Derivation of the volume of a triclinic unit cell:
The cell dimensions of a triclinic unit cell is
There are many choices for the primitive vectors in the triclinic system. So we are taking
Figure.1
Then,
Therefore,
This is the expression for the volume of a triclinic unit cell.
Derivation of the volume of a hexagonal unit cell:
The cell dimensions of a hexagonal unit cell is
Now substituting these values in the expression of the volume of a triclinic unit cell, we can get the exact expression for the hexagonal unit cell.
The above expression is for the volume of a hexagonal unit cell.
Want to see more full solutions like this?
Chapter 15 Solutions
ATKINS' PHYSICAL CHEMISTRY-ACCESS
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY