Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding. Concept introduction: Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite. Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

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Answer 1

Question

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

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• Show all significant resonance contributors and a resonance hybrid for the following molecule.

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One of the orbital interactions we did not consider in this chapter is that between an s AO from one atom and a p AO from another atom in the fashion shown. These orbitals will not interact while in this orientation. Explain why.

Answer 2

Question

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

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Answer 3

Question

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

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Answer 4

Question

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

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Answer 5

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

Answer 6

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

Answer 7

Chapter 14, Problem 14.8YT

Interpretation Introduction

Interpretation:

Each MO shown in Figure 14-21 is to be labeled as bonding, antibonding, or nonbonding.

Concept introduction:

Overlap of atomic orbitals (AOs) can be thought of as wave interference. It can be destructive overlap or constructive overlap. Constructive interference increases the electron density between the two nuclei (an antinode) and results in a molecular orbital (MO) of lower energy. The phases of the overlapping orbitals are the same in this case. Destructive interference reduces the electron density between the two nuclei and results in an MO of higher energy. The phases of such AOs are opposite.

Non-bonding MOs are formed when there is neither constructive nor destructive interference between the AOs. The energy of the MO is the same as the contributing AOs.

Answer 8

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Answer 9

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Answer 11

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2P Ch. 14 - Prob. 14.3P Ch. 14 - Prob. 14.4P Ch. 14 - Prob. 14.5P Ch. 14 - Prob. 14.6P Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8P Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10P

Solution Summary: The author explains that each MO shown in Figure 14-21 is labeled as bonding, antibonding or nonbond. Overlap of atomic orbitals can be considered as wave interference.

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