(a) Interpretation: A balance equation for the given reaction needs to be determined. Concept introduction: In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

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Answer 1

Question

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

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1. Which of the following statements is incorrect? (A) The reaction in which the rate equation corresponds to a stoichiometric equation is called an elementary reaction. (B) Molecularity of a reaction may not be equal to the order of reaction. (C) With increase in temperature, the rate constant obeying Arrhenius equation decreases. (D) Rate of a chemical reaction is independent of the concentration of the reactants for a zero order reaction. 2. The rate of a gas phase reaction is given by, kCACB. If the volume of the reaction vessel is reduced to l/3rd of its initial volume, then the reaction rate compared to the original rate will be _____ times. (A) 3 (C) 6 (B) 9 (D) 12 3. A given number of molecules (i.e., moles) of a particular chemical species have reacted or disappeared when any of the following occurs except (A) Combination (C) Isomerization (B) Decomposition (D) Isolation Please Answer all!

(a) Describe the term “integrated rate law” and briefly explain how it can be used tographically obtain the order of a reaction. (4)(b) Define the term “half-life of a substance” and briefly explain how it be used todetermine the order of the reaction and the rate constant for a first-order reaction. (4)

(a) With the help of a labelled diagram explain the role of activated complex in a reaction.(b) A first order reaction is 15% completed in 20 minutes. How long will it take to complete 60% of the reaction ?

Answer 2

Question

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

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Answer 3

Question

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Answer 6

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Answer 7

Chapter 14, Problem 14.126MP

Interpretation Introduction

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Answer 12

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Answer 13

Interpretation Introduction

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2A Ch. 14 - The rate law for the reaction...Ch. 14 - Prob. 14.4A Ch. 14 - The initial rates listed in the following...Ch. 14 - Prob. 14.6A Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8A Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10A

(a) Interpretation: A balance equation for the given reaction needs to be determined. Concept introduction: In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Solution Summary: The author explains how a balance equation for the given reaction needs to be determined.

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

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Chapter 14 Solutions

(a) Interpretation: A balance equation for the given reaction needs to be determined. Concept introduction: In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

Solution Summary: The author explains how a balance equation for the given reaction needs to be determined.

(a) Interpretation: A balance equation for the given reaction needs to be determined. Concept introduction: In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

(b) Interpretation: The rate law and the value of rate constant needs to be determined. Concept introduction: The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

(c) Interpretation: Whether the reaction takes place in a single-step or not needs to be explained. Concept introduction: The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

(d) Interpretation: A mechanism that consistent with the rate law needs to be determined. Concept introduction: The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

Want to see the full answer?

Chapter 14 Solutions

(a)

Interpretation:

A balance equation for the given reaction needs to be determined.

Concept introduction:

In the balance equation number of atoms of a particular element, i.e., reactant equals to the number of atoms of that element as a product.

(b)

Interpretation:

The rate law and the value of rate constant needs to be determined.

Concept introduction:

The relationship of the rate of the reaction to the rate constant and the concentrations of the reactants raised to some power is the rate of the reaction.

(c)

Interpretation:

Whether the reaction takes place in a single-step or not needs to be explained.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.

(d)

Interpretation:

A mechanism that consistent with the rate law needs to be determined.

Concept introduction:

The reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs.