Thermodynamics: An Engineering Approach
Thermodynamics: An Engineering Approach
9th Edition
ISBN: 9781259822674
Author: Yunus A. Cengel Dr., Michael A. Boles
Publisher: McGraw-Hill Education
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Chapter 13.3, Problem 100RP
To determine

To show that Zm=i=1kyiZi for a real gas mixture of k gases.

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What is the Δr xn G o (in KJ/mole) for a mole of an ideal gas as pressure changes from 0.1 Pa to 1 x10 5 Pa? (NOTE: Express answer in THREE SIGNIFICANT FIGURES.)
A cylinder contains oxygen at a pressure of 2.00 atm. The volume is 4.00 L, and the temperature is 300 K. Assume that the oxygen may be treated as an ideal gas. The oxygen is carried through the following processes: (i) Heated at constant pressure from the initial state (state 1) to state 2, which has T = 450 K. (ii) Cooled at constant volume to 250 K (state 3). (iii) Compressed at constant temperature to a volume of 4.00 L (state 4). (iv) Heated at constant volume to 300 K, which takes the system back to state 1. (a) Show these four processes in a pV-diagram, giving the numerical values of p and V in each of the four states. (b) Calculate Q and W for each of the four processes. (c) Calculate the net work done by the oxygen in the complete cycle. (d) What is the efficiency of this device as a heat engine? How does this compare to the efficiency of a Carnot-cycle engine operating between the same minimum and maximum temperatures of 250 K and 450 K?
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Chapter 13 Solutions

Thermodynamics: An Engineering Approach

Ch. 13.3 - A gas mixture consists of 20 percent O2, 30...Ch. 13.3 - Prob. 12PCh. 13.3 - Prob. 13PCh. 13.3 - Consider a mixture of two gases A and B. Show that...Ch. 13.3 - Is a mixture of ideal gases also an ideal gas?...Ch. 13.3 - Express Daltons law of additive pressures. Does...Ch. 13.3 - Express Amagats law of additive volumes. Does this...Ch. 13.3 - Prob. 18PCh. 13.3 - How is the P-v-T behavior of a component in an...Ch. 13.3 - Prob. 20PCh. 13.3 - Prob. 21PCh. 13.3 - Prob. 22PCh. 13.3 - Consider a rigid tank that contains a mixture of...Ch. 13.3 - Prob. 24PCh. 13.3 - Is this statement correct? The temperature of an...Ch. 13.3 - Is this statement correct? The volume of an...Ch. 13.3 - Is this statement correct? The pressure of an...Ch. 13.3 - A gas mixture at 300 K and 200 kPa consists of 1...Ch. 13.3 - Prob. 29PCh. 13.3 - Separation units often use membranes, absorbers,...Ch. 13.3 - Prob. 31PCh. 13.3 - The mass fractions of a mixture of gases are 15...Ch. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - An engineer has proposed mixing extra oxygen with...Ch. 13.3 - A rigid tank contains 0.5 kmol of Ar and 2 kmol of...Ch. 13.3 - A mixture of gases consists of 0.9 kg of oxygen,...Ch. 13.3 - Prob. 37PCh. 13.3 - One pound-mass of a gas whose density is 0.001...Ch. 13.3 - A 30 percent (by mass) ethane and 70 percent...Ch. 13.3 - Prob. 40PCh. 13.3 - Prob. 41PCh. 13.3 - A rigid tank that contains 2 kg of N2 at 25C and...Ch. 13.3 - Prob. 43PCh. 13.3 - Prob. 44PCh. 13.3 - Prob. 45PCh. 13.3 - Is the total internal energy of an ideal-gas...Ch. 13.3 - Prob. 47PCh. 13.3 - Prob. 48PCh. 13.3 - Prob. 49PCh. 13.3 - Prob. 50PCh. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - A mixture of nitrogen and carbon dioxide has a...Ch. 13.3 - The mass fractions of a mixture of gases are 15...Ch. 13.3 - A mixture of gases consists of 0.1 kg of oxygen, 1...Ch. 13.3 - An insulated tank that contains 1 kg of O2at 15C...Ch. 13.3 - An insulated rigid tank is divided into two...Ch. 13.3 - Prob. 59PCh. 13.3 - A mixture of 65 percent N2 and 35 percent CO2...Ch. 13.3 - Prob. 62PCh. 13.3 - Prob. 63PCh. 13.3 - Prob. 66PCh. 13.3 - Prob. 67PCh. 13.3 - Prob. 68PCh. 13.3 - Prob. 69PCh. 13.3 - The gas passing through the turbine of a simple...Ch. 13.3 - Prob. 71PCh. 13.3 - A pistoncylinder device contains 6 kg of H2 and 21...Ch. 13.3 - Prob. 73PCh. 13.3 - Prob. 74PCh. 13.3 - Prob. 75PCh. 13.3 - Prob. 76PCh. 13.3 - Prob. 77PCh. 13.3 - Prob. 78PCh. 13.3 - Prob. 79PCh. 13.3 - Prob. 81PCh. 13.3 - Fresh water is obtained from seawater at a rate of...Ch. 13.3 - Is it possible for an adiabatic liquid-vapor...Ch. 13.3 - Prob. 84PCh. 13.3 - Prob. 85RPCh. 13.3 - The products of combustion of a hydrocarbon fuel...Ch. 13.3 - A mixture of gases is assembled by first filling...Ch. 13.3 - Prob. 90RPCh. 13.3 - Prob. 91RPCh. 13.3 - Prob. 92RPCh. 13.3 - A rigid tank contains a mixture of 4 kg of He and...Ch. 13.3 - A spring-loaded pistoncylinder device contains a...Ch. 13.3 - Prob. 95RPCh. 13.3 - Reconsider Prob. 1395. Calculate the total work...Ch. 13.3 - Prob. 97RPCh. 13.3 - Prob. 100RPCh. 13.3 - Prob. 101RPCh. 13.3 - Prob. 102FEPCh. 13.3 - An ideal-gas mixture whose apparent molar mass is...Ch. 13.3 - An ideal-gas mixture consists of 2 kmol of N2and 4...Ch. 13.3 - Prob. 105FEPCh. 13.3 - Prob. 106FEPCh. 13.3 - An ideal-gas mixture consists of 3 kg of Ar and 6...Ch. 13.3 - Prob. 108FEPCh. 13.3 - Prob. 109FEPCh. 13.3 - Prob. 110FEPCh. 13.3 - Prob. 111FEP
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Thermodynamics - Chapter 3 - Pure substances; Author: Engineering Deciphered;https://www.youtube.com/watch?v=bTMQtj13yu8;License: Standard YouTube License, CC-BY