The mechanism of the reaction should be drawn. Concept introduction: Bromination: Alcohols brominated by using Phosphorus tribromide (Pbr 3) which provides corresponding brominated products. Chlorination: Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products. Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH 4 which provides alcohol.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

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Answer 5

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 6

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 7

Chapter 13, Problem 47PP

(a)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The mechanism of the reaction should be drawn.

Concept introduction:

Bromination:

Alcohols brominated by using Phosphorus tribromide (Pbr₃₎which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Prob. 1LTS Ch. 13.1 - Prob. 1PTS Ch. 13.1 - Prob. 2ATS Ch. 13.1 - Prob. 3CC Ch. 13.2 - Prob. 4CC Ch. 13.2 - Prob. 2LTS Ch. 13.2 - Prob. 5PTS Ch. 13.2 - Prob. 6ATS Ch. 13.3 - Prob. 7CC Ch. 13.3 - Prob. 8CC

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Chapter 13 Solutions