The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

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Answer 1

Question

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

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Chances Ad ~stract one 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $4th total Statistical pro 21 total 2 H A 2H 래 • 4H totul < 3°C-H werkest bund - abstraction he leads to then mo fac a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? рос 6 -વા J Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl

What is the lone pair or charge that surrounds the nitrogen here to give it that negative charge?

Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfox

Answer 2

Question

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

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Answer 3

Question

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

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Answer 4

Question

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

Expert Solution & Answer

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Answer 5

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

Answer 6

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

Answer 7

Chapter 13, Problem 46E

(a)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

Answer 8

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

Answer 9

(b)

Interpretation Introduction

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

Answer 10

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

Answer 11

(c)

Interpretation Introduction

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 13 - Q1. This graph shows the concentration of the...Ch. 13 - Q2. Dinitrogen monoxide decomposes into nitrogen...Ch. 13 - Q3. This plot shows the rate of the decomposition...Ch. 13 - Prob. 4SAQ Ch. 13 - Prob. 5SAQ Ch. 13 - Prob. 6SAQ Ch. 13 - Prob. 7SAQ Ch. 13 - Prob. 8SAQ Ch. 13 - Prob. 9SAQ Ch. 13 - Prob. 10SAQ

The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

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To determine: The order of the reaction consistent with the half-life of the reaction that gets shorter as the initial concentration is increased.

To determine: The order of the reaction consistent with a plot of the natural log of concentration of the reactant versus the time that yields a straight line.

To determine: The order of the reaction consistent with the half-life of the reaction that gets longer as the initial concentration is increased.

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