Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
Question
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Chapter 13, Problem 13.3DQ
Interpretation Introduction

Interpretation:

The reason for spin-lattice relaxation time of benzene in deuterated hydrocarbon solvent increases whereas that of polymer decreases has to be identified.

Concept Introduction:

Spin–lattice relaxation time:  The bulk nuclear magnetism develops by the weak interactions of nuclear magnetic moments of molecules having tumbling motions in solution.  This development of the bulk magnetic moment along an applied magnetic field is due spin-lattice relaxation.  It is characterized by a time constant called the spin–lattice relaxation time constant.

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