EBK ESSENTIAL ORGANIC CHEMISTRY
EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 8220100659461
Author: Bruice
Publisher: PEARSON
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Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

EBK ESSENTIAL ORGANIC CHEMISTRY, Chapter 12, Problem 45P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

EBK ESSENTIAL ORGANIC CHEMISTRY, Chapter 12, Problem 45P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

EBK ESSENTIAL ORGANIC CHEMISTRY, Chapter 12, Problem 45P , additional homework tip  3

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

EBK ESSENTIAL ORGANIC CHEMISTRY, Chapter 12, Problem 45P , additional homework tip  4

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PLEASE HELP Draw the products formed when cyclohexene is treated with each reagent.
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