ORGANIC CHEMISTRY-PRINT COMPANION (LL)
4th Edition
ISBN: 9781119659594
Author: Klein
Publisher: WILEY
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Chapter 1.2, Problem 2ATS
Interpretation Introduction
Interpretation: All the constitutional isomers for chlorofluorocarbons (CFCs) having molecular formula
Concept Introduction: The molecules that possess same molecular formula but differ in structural arrangement of atoms in the molecule are said to be isomers of each other.
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1. Read section 1.6. In the absence of formal charges, carbon forms four bonds, oxygen
forms two bonds and hydrogen forms only one covalent bond. Draw bond-line
formulas for 3 constitutional isomers of molecular formula C₂H8O.
For the compounds below, which, if any, exist as cis- or trans-isomers? Type the
number or numbers of the compound(s) (separated by a comma with no spaces). If
none of the compounds exist as cis- or trans-isomers, type none.
H₂C:
3
CH3
CH3
CH3
CH3
H₂C
Cl
2
4
-CH3
CH3
Draw the cis and trans isomers of 2-butene, CH3CHCHCH₂. Show all hydrogen atoms.
cis-2-butene
Incorrect
Y
trans-2-butene
Incorrect
YA
H
Chapter 1 Solutions
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
Ch. 1.2 - Prob. 1LTSCh. 1.2 - Prob. 2ATSCh. 1.2 - Prob. 2LTSCh. 1.3 - Prob. 3LTSCh. 1.3 - Prob. 4PTSCh. 1.3 - Prob. 5PTSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 7PTSCh. 1.4 - Prob. 8PTSCh. 1.4 - Prob. 9ATS
Ch. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 10PTSCh. 1.5 - Prob. 11ATSCh. 1.5 - Prob. 12ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 14ATSCh. 1.7 - Prob. 7LTSCh. 1.7 - Prob. 17ATSCh. 1.10 - Prob. 18CCCh. 1.10 - Prob. 20CCCh. 1.10 - Prob. 8LTSCh. 1.10 - Prob. 21PTSCh. 1.10 - Nemotin is a compound that was first isolated from...Ch. 1.10 - Prob. 23CCCh. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 24PTSCh. 1.11 - Prob. 25PTSCh. 1.11 - Prob. 26PTSCh. 1.11 - Prob. 27ATSCh. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 29ATSCh. 1.13 - Prob. 11LTSCh. 1.13 - Prob. 31ATSCh. 1 - Prob. 32PPCh. 1 - Prob. 33PPCh. 1 - Prob. 34PPCh. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Nicotine is an addictive substance found in...Ch. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 59PPCh. 1 - Prob. 63ASPCh. 1 - Prob. 64ASPCh. 1 - Prob. 66ASPCh. 1 - Prob. 69ASPCh. 1 - Prob. 71ASPCh. 1 - Prob. 72ASPCh. 1 - Prob. 75IP
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- 5. How many isomers are possible for C6H4(CH3)Cl, a benzene derivative? 1 2 3arrow_forward1. Considering compounds that have the same number of carbon atoms, explain why alkanes and cycloalkanes have different molecular formulas but alkenes and cycloalkanes have the same molecular formulas. 2. Draw the condensed or line-angle structure for an alkene with the formula C5H10. 3. Draw the condensed or line-angle structure for 4 more C5H10 isomers (2 additional alkenes and 2 cyclic isomers).arrow_forwardIf you rotate the hydrogen atoms to a different position in a a model of C2H6 by turning about the central C—C bond, do you get different structural (or constitutional) isomers of C2H5Cl?arrow_forward
- There are 17 constitutional isomers with the molecular formula of C5H13N. Draw all 17 of these isomers as skeletal structures and give the SMILES for each.arrow_forwardDraw two constitutional isomers that share the molecular formula C3H,CI. Your structures will have the same molecular formula but will have different connectivities.arrow_forwardPentane has several isomers. Which of the following condensed formulas is NOT an isomer of pentane? O CH3CH₂C (CH3)2 O CH2(C2H5)2 O CH3CH₂CH₂CH2CH3 O CH3C(CH3)3arrow_forward
- III. Draw two isomers for the following compounds, in line structural formula only and name them. 1. Alkane with molecular formula C6H14 2. ● ● . ● Cis isomer (Line structure) ● IUPAC name of cis isomer ● Trans isomer (Line structure) IUPAC name of trans isomer Isomer 1 (Line structure) IUPAC name of Isomer 1 Isomer 2 (Line structure) IUPAC name of Isomer 2 .arrow_forwardDraw the structure of the four constitutional isomers of molecular formula C 3H 6Br 2.arrow_forwardDraw the cis and trans isomers of 2-butene, CH3CHCHCH₂. Show all hydrogen atoms. cis-2-butene Incorrect Y trans-2-butene Incorrect CH 3+ yo C H 3+ Harrow_forward
- Consider C2 H6 O3. How many isomers can be drawn that have three O H groups?arrow_forwardHexane has several isomers. Which of the following condensed formulas is not an isomer of hexane? O (C2H5)2CHCH3 O (CH3)2CHCH(CH3)2 O CH3C(CH3)3 O C2H5C(CH3)3arrow_forwardMolecules that have the same molecular formula, but different atomic connections are called constitutional isomers. Draw and name the five constitutional isomers of C6H14. Is this correct answer from this paper that I draw for the name the five constitutional isomers of C6H14? Can you explain to me that why is the different atomic connections are called constitutional isomers?arrow_forward
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