Concept explainers
12-23 Draw a structural formula for each compound.
- 3-Chloropropene
- 3-Methylcyclohexene
- 1,2-Dimethylcyclohexene
- /runs-3,4-Dimethyl-3-heptene
- Cydopropene
- 3-Hexyne
(a)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space.
In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as . The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
3-Chloropropene.
Carbon atoms in the longest chain are 3.
-ene means a double bond is present at Carbon 1.
Chlorine at Carbon 3.
Structure.
(b)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space. In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as . The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
3-Methylcyclohexene.
Carbons in longest chain=6.
Cyclo means a cyclic hydrocarbon.
-ene means a double bond is present at Carbon 1.
Methyl at Carbon 3.
Structure.
(c)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space. In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
1,2-Dimethylcyclohexene.
Carbons in longest chain=6.
Cyclo means a cyclic hydrocarbon.
-ene means a double bond is present at Carbon 1.
Methyl at Carbon 1 and 2.
Structure.
(d)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space. In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
Trans-3,4-Dimethyl-3-heptene.
Carbons in longest chain=7.
-ene means a double bond is present at Carbon3.
Methyl at Carbon 3 and 4.
Trans isomer that means the two methyl are opposite in direction.
Structure.
(e)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space. In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as . The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
Cyclopropene.
Carbons in longest chain=3.
-ene means a double bond is present at Carbon1.
Cyclo means a cyclic hydrocarbon.
Structure.
(f)
Interpretation:
To draw the structural formula for the compound.
Concept Introduction:
Structural formula is the spatial arrangement of atoms of a molecule in space. In the condensed formula is a line-angle formula, the symbol for carbon and hydrogen atoms are not shown. Only carbon-carbon bonds are shown using lines. Single bonds are shown as double bond as and triple bond as . The carbon atoms are represented as vertices and end of lines.
Answer to Problem 12.23P
Explanation of Solution
3-Hexyne.
Carbons in longest chain=6.
-yne means a triple bond is present at Carbon3.
Structure.
Want to see more full solutions like this?
Chapter 12 Solutions
Introduction to General, Organic and Biochemistry
- 12-45 Draw a structural formula for the product of each reaction. 1-Methylcyclohexene + Br2 1,2-Dimethylcyclopentene + Cl2arrow_forward12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethanearrow_forward12-27 Explain why each name is incorrect and then write a correct name. 2-Ethyl-l-propene 5-lsopropylcyclohexene 4-Methyl-4-hexene 2-sec-Butyl-l-butene 6,6-Dimethylcyclohexene 2-Ethyl-2-hexenearrow_forward
- 12-40 Define alkene addition reaction. Write an equation for an addition reaction of propene.arrow_forwardDraw at least two structural formulas for each of the following. (Several constitutional isomers are possible for each part.) An alkene with six carbons A cycloalkene with six carbons An alkyne with six carbons An aromatic hydrocarbon with eight carbonsarrow_forward13-53 Write the structural formula for the product of each reaction.arrow_forward
- 12-13 What is the difference in structure between a saturated hydrocarbon and an unsaturated hydrocarbon?arrow_forward/3-Ocimene, a triene found in the fragrance of cotton blossoms and several essential oils, has the 1UPAC name czs-3,7-dimethyl-l,3,6-octatriene. (Cis refers to the configuration of the double bond between carbons 3 and 4, the only double bond in this molecule about which cis-trans isomerism is possible.) Draw a structural formula for /3-ocimene.arrow_forwardGive the IUPAC names for the eight isomeric halogenated hydrocarbons that have the molecular formula C5H11Cl.arrow_forward
- The heat of combustion of methane, a component of natural gas, is 212 kcal/mol. That of propane, a component of LP gas, is 530 kcal/mol. On a gram- for-gram basis, which hydrocarbon is the better source of heat energy?arrow_forward13-3 What is the difference in structure between a saturated and an unsaturated hydrocarbon?arrow_forward12-25 Write the IUPAC name for each unsaturated hydrocarbon. (d)c=ch2 ch3ch,ch2arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning