(a)
Interpretation:
To find the heat liberated of isothermal mixing at 300 K
Concept Introduction:
We find the Excess enthalpy of H2SO4of pure and 25-wt-% from the H-x diagram of H2SO4
Then we find the enthalpy of Pure water.
The heat of mixing, Q is as given below,
Where,
Mass of H2O= m1
Mass of H2SO4= m2 Mass of 25-wt-% H2SO4= m3 Total mass = m4
Enthalpy of Pure H2O = H1 Enthalpy of Pure H2SO4 (100-wt-%) = H2 Enthalpy of 25-wt-% H2SO4 = H3 Total enthalpy = H4
Mass fraction of H2O= x1
Mass fraction of H2SO4= x2 Mass fraction of 25-wt-% H2SO4= x3 Total mass fraction of H2SO4= x4
(b)
Interpretation:
To find the temperature of the intermediate solution formed
Concept Introduction:
We find the Excess enthalpy of H2SO4of pure and 25-wt-% from the H-x diagram of H2SO4
Then we find the enthalpy of Pure water.
The heat of mixing, Q is as given below,
Where,
Mass of H2O= m1
Mass of H2SO4= m2 Total mass = m3
Enthalpy of Pure H2O = H1 Enthalpy of Pure H2SO4 (100-wt-%) = H2 Total enthalpy = H3
Mass fraction of H2O= x1
Mass fraction of H2SO4= x2 Total mass fraction of H2SO4= x3
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Introduction to Chemical Engineering Thermodynamics
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