(a) Interpretation: The structure corresponding to ( 1 E , 4 R ) − 1 , 4 − dimethylcyclodecene is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

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Answer 1

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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(a) Draw all possible stereoisomers of 4-methylnon-2-ene, and name each isomer, including its E,Z and R,S prefixes. (b) Label two pairs of enantiomers. (c) Label four pairs of diastereomers.

Draw a three-dimensional structure for each compound, and star all asymmetric carbon atoms. Draw the mirror image for each structure, and state whether you have drawn a pair of enantiomers or just the same molecule twice. Build molecular models of any of these examples that seem difficult to you. (a) ОН (b) (c) NH, ОН СH—CH—СООН | pentan-2-ol pentan-3-ol alanine (d) 1-bromo-2-methylbutane (e) chlorocyclohexane (f) cis-1,2-dichlorocyclobutane (h) (i) H CH; "H H. H CH, H

(A)Menthol, used to flavor various foods and tobacco, is the most stable stereoisomer of 2-isopropyl-5-methylcyclohexanol. Draw its most stable conformation. Is the hydroxyl group cis or trans to the isopropyl group? To the methyl group? (b) Neomenthol is a stereoisomer of menthol. That is, it has the same constitution but differs in the arrangement of its atoms in space. Neomenthol is the second most stable stereoisomer of 2-isopropyl-5methylcyclohexanol; it is less stable than menthol but more stable than any other stereoisomer. Write the structure of neomenthol in its most stable conformation.

Answer 2

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 3

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 4

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 5

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 6

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 7

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 8

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 11

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10.1 - Prob. 1P Ch. 10.2 - Problem 10.2 How many degrees of unsaturation are...Ch. 10.3 - Give the IUPAC name for each alkene. abcde Ch. 10.3 - Give the IUPAC name for each polyfunctional...Ch. 10.3 - Prob. 9P Ch. 10.6 - Linolenic acidTable 10.2 and stearidonic acid are...Ch. 10.7 - Prob. 12P Ch. 10.9 - Problem 10.13 What product is formed when each...Ch. 10.9 - Prob. 14P Ch. 10.10 - Problem 10.15 Draw the products formed when each...

Solution Summary: The author explains the systematic naming of organic compound by IUPAC. The prefix E and Z depends upon the location of the higher priority groups.

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Chapter 10 Solutions