The rate of the reaction should be identified. Concept introduction: Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom. Inductive effect : An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule. Hyperconjugation effect : hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system. The increasing order of radical stability is given below Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 1

Question

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 2

Question

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 3

Question

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 4

Question

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 5

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 6

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 7

Chapter 10, Problem 41IP

Interpretation Introduction

Interpretation:

The rate of the reaction should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 10.1 - Prob. 1CC Ch. 10.1 - Prob. 1LTS Ch. 10.1 - Prob. 2PTS Ch. 10.1 - Prob. 3PTS Ch. 10.1 - Prob. 4ATS Ch. 10.1 - Prob. 2LTS Ch. 10.1 - Prob. 5PTS Ch. 10.1 - Prob. 6PTS Ch. 10.1 - Prob. 7ATS Ch. 10.2 - Prob. 3LTS

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Chapter 10 Solutions