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Concept explainers
Interpretation:
The structures of the two ethers, apart from
Concept introduction:
Two molecules of alcohol condense to form an ether when heated under acidic conditions. The reaction occurs via an
Under acidic conditions, the hydroxyl (
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Chapter 10 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
- 1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise? 2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia. (i) What do you understand by the term nucleophile? (ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles? 3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?arrow_forward10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best matches the expected products? A) Acid-catalyzed dehydration B) Nucleophilic substitution reaction C) Ether cleavage reaction D) Nucleophilic addition-elimination reactionarrow_forward4. identify the structure of A and B in the following synthetic scheme: Write out complete reactions for each step, showing the structure of all reactants and products. (a) cyclohexanol +Na2Cr2O7/H2SO4, H2O -------> A (b) A + Et2NH/H2SO4 ----->Barrow_forward
- How could you convert each of the following compounds into butanoic acid? Write each step showing all reagents. (a) 1-Butanol (b) 1-Bromobutane (c) 1-Butenearrow_forwarda) When (Z)-3-methylhex-3-ene undergoes hydroboration–oxidation, two isomeric products are formed. Give their structures, and label each asymmetric carbon atom as (R) or (S). What is the relationship between these isomers?arrow_forward1.Name and draw the products of each reaction. (a) 1-propanol + hydrobromic acid → HSO (b) 1-pentanol A HSO (c) N-propylmethanamide + water (d) 3-methyl oct-2-ene + hydrochloric acid - (e) 2-fluoro-2-phenyl butanoic acid + ethanolarrow_forward
- A certain hydrocarbon had the molecular formula C18H30 and contained two triple bonds. Ozonolysis gave CH₂(CH₂)CO₂H and HO₂CCH₂CH₂CO₂H as the only products. Draw a reasonable structure for this hydrocarbon. Click and drag to start drawing a structure.arrow_forwardWhen (1-bromoethyl)cyclopentane is heated in water for an extended period of time, SIX products result: three alcohols and three alkenes. Draw the three alcoholsarrow_forwardIdentify all possible product(s) in the following reactions. a) 1-bromocyclohexane with sodium hydroxide.b) 2-chloro-2-methylpentane with waterarrow_forward
- What reaction conditions are needed to convert (R)-2-ethyl-2-methyloxirane to (S)-2- methylbutane-1,2-diol ?arrow_forwardShow how you would convert(a) oct-3-yne to cis-oct-3-ene.(b) pent-2-yne to trans-pent-2-ene.(c) cis-cyclodecene to trans-cyclodecene.(d) but-1-yne to cis-hex-3-enearrow_forwardIQ3 نقطة واحدة Name the following heterocyclic ethers (a) إجابتك نقطة واحدة Name the following heterocyclic ethers H. CH,CH3 (d) CH,CH, H. إجابتك نقطة واحدة Name the following heterocyclic ethers -CH3 CH; () Br إجابتك. II >arrow_forward
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