Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 10, Problem 10.22P
Interpretation Introduction

Interpretation:

To find the ratio of fugacity of steam at initial state to fugacity at the final state from 9000 kPa and 400 0C to 300 kPa.

Concept Introduction :

Gibbs energy is given as below,

  G=Γ(T)+RTln(f)

and it is related to enthalpy and entropy as given below,

  G=HTS

Where,

G = Gibbs Energy

T1 = Initial Temperature = 400 0C

H1 = Initial Enthalpy

S1 = Initial Entropy

f1 = Initial fugacity

T2 = Final Temperature = 400 0C

H2 = Final Enthalpy

S2 = Final Entropy

f2 = Final fugacity

R = Universal Gas constant = 8.314 J/molK

m = Molecular weight = 18 g/mol

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