Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
8th Edition
ISBN: 9781305095236
Author: Maria Cecilia D. De Mesa, Thomas D. Mcgrath
Publisher: Cengage Learning
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Chapter 1, Problem 24QAP
Which of the following statements use only exact numbers?
(a) The temperature in our dorm room is kept at 72 °F.
(b) 1 bought 6 eggs, 2 cookies, and 5 tomatoes at the farmers' market.
(c) There are 1×109 nanometers in 1 meter.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 1 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
Ch. 1 - Classify each of the following as element,...Ch. 1 - Classify each of the following as element,...Ch. 1 - Classify the following as solution or...Ch. 1 - Classify the following as solution or...Ch. 1 - Prob. 5QAPCh. 1 - Prob. 6QAPCh. 1 - Write the symbol for the following elements. (a)...Ch. 1 - Prob. 8QAPCh. 1 - Write the name of the element represented by the...Ch. 1 - Write the name of the element represented by the...
Ch. 1 - What instrument would you use to determine (a) the...Ch. 1 - What instrument would you use to (a) measure the...Ch. 1 - A glass of lukewarm milk is suggested for people...Ch. 1 - A recipe for apple pie calls for a preheated 350F...Ch. 1 - Gallium is one of the few metals that can melt at...Ch. 1 - Computers are not supposed to be in very warm...Ch. 1 - How many significant figures are in each of the...Ch. 1 - How many significant figures are there in each of...Ch. 1 - Round off the following quantities to the...Ch. 1 - Round off the following quantities to the...Ch. 1 - Prob. 21QAPCh. 1 - Prob. 22QAPCh. 1 - Which of the following statements use only exact...Ch. 1 - Which of the following statements use only exact...Ch. 1 - A basketball game at the University of...Ch. 1 - A listing of a house for sale states that there...Ch. 1 - Calculate the following to the correct number of...Ch. 1 - Perform the indicated calculations. Write your...Ch. 1 - Prob. 29QAPCh. 1 - The volume of a square pyramid is (1/3)Bh where B...Ch. 1 - Write the appropriate symbol in the blank (,,or=)....Ch. 1 - Write the appropriate symbol in the blank (,,or=)....Ch. 1 - Convert 22.3 mL to (a) liters (b) in3 (c) quartsCh. 1 - Convert 0.2156 L to (a) mL (b) in3 (c) quartsCh. 1 - The height of a horse is usually measured in...Ch. 1 - At sea, distances are measured in nautical miles...Ch. 1 - The unit of land measure in the English system is...Ch. 1 - A gasoline station in Manila, Philippines, charges...Ch. 1 - A lap in most tracks in the United States is 0.25...Ch. 1 - Cholesterol in blood is measured in milligrams of...Ch. 1 - Prob. 41QAPCh. 1 - The area of the 48 contiguous states is 3.02106...Ch. 1 - Prob. 43QAPCh. 1 - In the old pharmaceutical system of measurements,...Ch. 1 - The cup is a measure of volume widely used in...Ch. 1 - The egg whites from four large eggs occupy a...Ch. 1 - A metal slug weighing 25.17 g is added to a flask...Ch. 1 - A solid with an irregular shape and a mass of 11.3...Ch. 1 - A waterbed filled with water has the dimensions...Ch. 1 - Wire is often sold in pound spools according to...Ch. 1 - Air is 21% oxygen by volume. Oxygen has a density...Ch. 1 - The unit for density found in many density tables...Ch. 1 - Magnesium sulfate (MgSO4) has a solubility of 38.9...Ch. 1 - Potassium sulfate has a solubility of 15 g/ 100 g...Ch. 1 - Sodium bicarbonate (baking soda) is commonly use...Ch. 1 - Magnesium chloride is an important coagulant used...Ch. 1 - The solubility of lead nitrate at 100C is 140.0...Ch. 1 - Radiation exposure to human beings is usually...Ch. 1 - The following data refer to the element...Ch. 1 - A supersaturated sugar solution (650.0 g sugar in...Ch. 1 - The density of wind-packed snow is estimated to be...Ch. 1 - The dimensions of aluminum foil in a box for sale...Ch. 1 - The Kohinoor Diamond (d=3.51g/cm3) is 108 carats....Ch. 1 - A pycnometer is a device used to measure density....Ch. 1 - Prob. 65QAPCh. 1 - Label each of the properties of iodine as...Ch. 1 - How do you distinguish (a) chemical properties...Ch. 1 - What is the difference between (a) mass and...Ch. 1 - Mercury, ethyl alcohol, and lead are poured into a...Ch. 1 - How many significant figures are there in the...Ch. 1 - Consider the following solubility graph. (a) At...Ch. 1 - Given the following solubility curves, answer the...Ch. 1 - A Different civilization on a distant planet has...Ch. 1 - At what point is the temperature in F exactly...Ch. 1 - Prob. 75QAPCh. 1 - A laboratory experiment requires 12.0 g of...Ch. 1 - An average adult breathes about 8.50103 L of air...Ch. 1 - A student determines the density of a metal by...
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