Organic Chemistry, Books a la Carte Edition (9th Edition)
9th Edition
ISBN: 9780134160382
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 1, Problem 1.34SP
Draw Lewis structures for
- a. two compounds of formula C4H10
- b. two compounds of formula C2H6O
- c. two compounds of formula C2H7N
- d. three compounds of formula C2H7NO
- e. three compounds of formula C2H8O2
- f. three compounds of formula C2H4O
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Draw the Lewis structure for each organic compound from its condensed structural formula.a. C2H4 b. CH3NH2 c. HCHOd. CH3CH2OH e. HCOOH
5. Draw Lewis structures for each molecular formula.
H
A. C₂H4Cl₂ (two isomers)
B. C3H8O (three isomers)
C. C6H14 (five isomers)
C-H-C-H-CI-CI
C-H-C-H-CI-CI
Draw a Lewis structure for each ion.
a. CH3O−
b. HC2−
c. (CH3NH3)+
d. (CH3NH)−
Chapter 1 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
Ch. 1.2C - a. Nitrogen has relatively stable isotopes...Ch. 1.4 - Draw Lewis structures for the following compounds....Ch. 1.5 - Write Lewis structures for the following molecular...Ch. 1.5 - Circle any lone pairs (pairs of nonbonding...Ch. 1.6 - Use electronegativities to predict the direction...Ch. 1.8 - Prob. 1.6PCh. 1.9B - Draw the important resonance forms for the...Ch. 1.9B - Prob. 1.8PCh. 1.9B - Prob. 1.9PCh. 1.9B - Use resonance structures to identify the areas of...
Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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- Draw Lewis structures for each molecular formula a. C2H4CCl2 (two isomers) b. C3H8O (three isomers) c. C3H6 (two isomers)arrow_forwardDraw Lewis structures for tye following molecules. a.) Atom "X" has 4 valence electrons and Atom "Y" has 6 valence electrons. Draw the Lewis structure for the molecule XY2, showing all lone pairs and formal charges when necessary b.) Atom "M" has 5 valence electrons and Atom "L" has 7 valence electrons. Draw the Lewis structure for the molecule M2L4, showing all lone pairs and formal charges when necessaryarrow_forwardWhat is the relationship between the following compounds? A. constitutional isomers B. different representations of the same molecule C. different molecules D. isotopes E. resonance structuresarrow_forward
- 5. T / 1 Write the name of each compound .arrow_forwarda. Draw two Lewis structures for C2H6O. b. Draw three Lewis structures for C3H8O.arrow_forwardGive the total number of valence electrons in the following molecule. a. N₂O5 b. H₂S c. C₂H6 d. SO2 valence electrons valence electrons valence electrons valence electronsarrow_forward
- 12. Draw Lewis structures for these compounds. From your Lewis structures draw structural formulas.arrow_forward1.44 Draw one valid Lewis structure for each compound. Assume the atoms are arranged as drawn. H HCC NO H a. CH₂N₂ HCNN H H b. CH₂NO₂ HCNO HO C. CH3CNO d. (CH₂CN) HC CN H 1.45 Draw an acceptable Lewis structure from each condensed structure, such that all atoms have zero formal charge. a. diethyl ether, (CH3CH₂)2O, the first general anesthetic used in medical procedures b. acrylonitrile, CH₂CHCN, starting material used to manufacture synthetic Orlon fibers c. dihydroxyacetone, (HOCH₂)₂CO, an ingredient in sunless tanning products d. acetic anhydride, (CH3CO)2O, a reagent used to synthesize aspirinarrow_forwardPROVISIONAL LEWIS STRUCTURES T01/S01 For each provisional structure, identify if it is the correct Lewis structure (C) or if it needs to be modified according to procedure MA or MB to obtain the correct Lewis structure. MA. Form multiple bonds to the central atom using lone pair on the terminal atom(s) until the central atom has an octet (or septet). MB. Form multiple bonds to the central atom using lone pair on the terminal atom(s) until the central atom has a formal charge of zero (0) or until two double bonds are formed. A provisional structure has the valence electrons distributed in order as (1) a bond between each pair of atoms, (2) an octet for each ligand (terminal) atom or ligand group (CH3, NH2 or OH) and (3) any remaining electrons on the central atom.arrow_forward
- Determine if the structural formula below are acceptable Lewis structures for organic compounds. Point out the problems in cases where structure is invalid. CH3 CH;-N-CH-CH3 ČH3 A. This structure is correct because the valance of Nitrogen is complete. B. This is not a correct Lewis structure because Nitrogen can accommodate more atoms. C. This is not a correct Lewis structure because Nitrogen has a charge if it does not have three bonds. D. This is a correct Lewis structure.arrow_forwardWhich of the following molecules has/ have resonance structures? Select one or more: a.CH2=CH2 b.CH3–OH c.CH2=CH–O– d.CH3–O–CH3arrow_forward3. Complete the following for the formula PCl2I (there is only 1 central atom). Draw a plausible Lewis Structure. Name the electron geometry associated with your structure above. Name the molecular shape associated with your structure above. Draw a 3D representation of your structure including approximate bond angles. Would your structure be polar or nonpolar? Be sure to show or explain how you determined this.arrow_forward
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