A rigid vessel of volume
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Thermodynamics, Statistical Thermodynamics, & Kinetics
- At the critical point for carbon dioxide, the substance is very far from being an ideal gas. Prove this statement by calculating the density of an ideal gas in g/cm3 at the conditions of the critical point and comparing it with the experimental value. Compute the experimental value from the fact that a mole of CO2 at its critical point occupies 94 cm3.arrow_forwardA 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to 317 K, what is the pressure of the CO2?arrow_forwardA 0.526 g sample of a metal, M, reacts completely with sulfuric acid according to M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g) A volume of 243 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. Calculate the molar mass of the metal.arrow_forward
- What is the temperature in K of 0.500 mole of neon in a 2.00L vessel at 4.32 bar? R = 0.08314 L· bar/mol·K.arrow_forwardA 0.244 g sample of a metal, M, reacts completely with sulfuric acid according to M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g) A volume of 255 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. The vapor pressure of water at 25 °C is 23.8 Torr. Calculate the molar mass of the metal.arrow_forwardA 1.00 LL flask is filled with 1.45 gg of argon at 25 ∘C∘C. A sample of ethane vapor is added to the same flask until the total pressure is 1.400 atm. What is the partial pressure of ethane, PethanePethaneP_ethane, in the flask? Express your answer to three significant figures and include the appropriate units.arrow_forward
- Q.27. A 3.00 L sample of NH; gas at 100.0 kPa is cooled from 500.0 K to 300.0 K and its pressure is reduced to 80.0 kPa. What is the new volume of the gas?arrow_forwardWhen limestone (solid CaCO3) is heated, it decomposes into lime (solid CaO) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete - the lime absorbs CO₂ from the air and turns back into hard, durable limestone. Suppose a limekiln of volume 800. L is pressurized with carbon dioxide gas to 14.9 atm, and heated to 960.0 °C. When the amount of CO, has stopped changing, it is found that 3.96 kg of CaCO, have appeared. Calculate the pressure equilibrium constant K, this experiment suggests for the equilibrium between CaCO3 and CaO at 960.0 °C. Round your answer to 2 significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for K, does not match the accepted value. K = 3.07 рarrow_forwardA 0.495 g sample of a metal, M, reacts completely with sulfuric acid according to M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g) A volume of 225 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. The vapor pressure of water at 25 °C is 23.8 Torr. Calculate the molar mass of the metal. molar mass= ? g/molarrow_forward
- When limestone (solid CACO) is heated, it decomposes into lime (solid CaO) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete - the lime absorbs CO, from the air and turns back into hard, durable limestone. Suppose a limekiln of volume 750. L is pressurized with carbon dioxide gas to 15.1 atm, and heated to 1100. °C. When the amount of CO, has stopped changing, it is found that 4 kg of CaCO, have appeared. Calculate the pressure equilibrium constant K, this experiment suggests for the equilibrium between CaCO, and CaO at 1100. °C. Round your answer to 2 significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for K, does not match the accepted value. K, = [] x10 Submit Assignment Continue 2021 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center Accessibility MacBook Air DD 吕口 888 F10 F7…arrow_forwardThe van der Waals coefficients of monatomic krypton gas are a=0.2318a=0.2318 m66Pa/mol22 and b=39.78×106b=39.78×106 m33/mol. What is the change in temperature, ΔT, when one mole of krypton gas undergoes a Joule free expansion from 0.1 L to 10 L?arrow_forwardA 0.487 g sample of a metal, M, reacts completely with sulfuric acid according to the reaction M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g) A volume of 225 mL of hydrogen gas is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 1.0079 bar and the temperature is 25 °C. The vapor pressure of water at 25 °C is 0.03167 bar. Calculate the molar mass of the metal.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningPhysical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,