Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Dissolving 3.03 g of CaCl₂(s) in 154.4 g of water in a calorimeter at 22.5 °C causes the temperature to rise to 25.7 °C. What is the change in enthalpy for this dissolution (in J), assuming the specific heat of the resulting solution is 4.184 J/g °C?arrow_forwardHelparrow_forwardA constant pressure calorimeter contains 286 g of water at 20.0 °C. A 13.41 g of substance X (molar mass 154 g/mol) at 20.0°C was dissolved in this water. The temperature of the solution increased to 23.5 °C. Assuming the specific heat of the mixture is 4.184 J g‑1°C‑1, and the density of the solution is 1.00 g/cm3, calculate the enthalpy change (in kJ) for the dissolution of 1 mole of X.arrow_forward
- Potassium nitrate, KNO3, has a molar mass of 101.1 g/mol. In a constant-pressure calorimeter, 48.1 g of KNO3KNO3 is dissolved in 229 g of water at 23.00 °C. KNO3(s)−→−−H2OK+(aq)+NO−3(aq) The temperature of the resulting solution decreases to 17.80 °C. Assume that the resulting solution has the same specific heat as water, 4.184 J/(g·°C), and that there is negligible heat loss to the surroundings. How much heat was released by the solution? ?soln= kJ What is the enthalpy of the reaction? Δ?rxn= kJ/molarrow_forwardMeasurements show that the energy of a mixture of gaseous reactants decreases by 373. kJ during a certain chemical reaction, which is carried out at a constant pressure. Furthermore, by carefully monitoring the volume change it is determined that 136. kJ of work is done on the mixture during the reaction. Calculate the change in enthalpy of the gas mixture during the reaction. Round your answer to 3 x10 significant digits. exothermic Is the reaction exothermic or endothermic? endothermicarrow_forwardA student followed the procedure in this experiment , using 29.5 mL of 2.41 molar HCl and 31.5 mL of 2.41 molar NaOH , with both solutions having an initial temperature of 21.9 °C. After mixing , a maximum temperature of 31.0 °C is measured . The final mass of the mixture was found to be 62.201 grams . For this problem , assume the specific heat of the solution is 4.18 J/g °C. What is the heat transferred by this reaction, in Joules?arrow_forward
- When a 6.00 g6.00 g sample of KClKCl is dissolved in water in a calorimeter that has a total heat capacity of 4.47 kJ⋅K−1,4.47 kJ⋅K−1, the temperature decreases by 0.310 K.0.310 K. Calculate the molar heat of solution of KCl.arrow_forwardIn a constant‑pressure calorimeter, 60.0 mL of 0.320 M Ba(OH)2 was added to 60.0 mL of 0.640 M HCl.The reaction caused the temperature of the solution to rise from 24.50 ∘C to 28.86 ∘C. If the solution has the same density and specific heat as water (1.00 g/mLand 4.184J/g⋅°C, respectively), what is ΔH for this reaction (per mole H2O produced)? Assume that the total volume is the sum of the individual volumes. ΔH= _________ kJ/mol H2Oarrow_forwardA student dissolves 12.3 g of ammonium chloride (NH4Cl) in 200. g of water in a well-insulated open cup. He then observes the temperature of the water fall from 21.0 °C to 17.4 °C over the course of 3.6 minutes. Use this data, and any information you need from the ALEKS Data resource, to answer the questions below about this reaction: NH4Cl (s) NH(aq) + CT (aq) You can make any reasonable assumptions about the physical properties of the solution. Be sure answers you calculate using measured data are rounded to 2 significant digits. Note for advanced students: it's possible the student did not do the experiment carefully, and the values you calculate may not be the same as the known and published values for this reaction. Is this reaction exothermic, endothermic, or neither? If you said the reaction was exothermic or endothermic, calculate the amount of heat that was released or absorbed by the reaction in this case. Calculate the reaction enthalpy ΔΗ per mole of NH Cl. rxn n exothermic…arrow_forward
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