You have a solution consisting of 0.10 M PO4 3– and 0.10 M I - . You add 0.10 M silver nitrate dropwise to this solution. Given that the Ksp for AgI is 1.5 × 10–16 , and that for Ag3PO4 is 1.3 × 10–20 , which of the following will precipitate first? (show work) a) Silver iodide b) Silver Phosphate  c) Silver Nitrate d) none of

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Chapter17: Solubility And Complex-ion Equilibria
Section: Chapter Questions
Problem 17.86QP
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You have a solution consisting of 0.10 M PO4 3– and 0.10 M I - . You add 0.10 M silver nitrate dropwise to this solution. Given that the Ksp for AgI is 1.5 × 10–16 , and that for Ag3PO4 is 1.3 × 10–20 , which of the following will precipitate first? (show work)

a) Silver iodide

b) Silver Phosphate 

c) Silver Nitrate

d) none of these

 
 
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