Skip to main content
close
Homework Help is Here – Start Your Trial Now!
arrow_forward
Literature guides
Concept explainers
Writing guide
Popular textbooks
Popular high school textbooks
Popular Q&A
Business
Accounting
Business Law
Economics
Finance
Leadership
Management
Marketing
Operations Management
Engineering
AI and Machine Learning
Bioengineering
Chemical Engineering
Civil Engineering
Computer Engineering
Computer Science
Cybersecurity
Data Structures and Algorithms
Electrical Engineering
Mechanical Engineering
Language
Spanish
Math
Advanced Math
Algebra
Calculus
Geometry
Probability
Statistics
Trigonometry
Science
Advanced Physics
Anatomy and Physiology
Biochemistry
Biology
Chemistry
Earth Science
Health & Nutrition
Health Science
Nursing
Physics
Social Science
Anthropology
Geography
History
Political Science
Psychology
Sociology
learn
writing tools
expand_more
plus
study resources
expand_more
Log In
Sign Up
expand_more
menu
SEARCH
Homework help starts here!
ASK AN EXPERT
ASK
Science
Chemistry
Why is one stereoisomer of 1,2-dimethylcyclopropane more stable than the other? wwwww
Why is one stereoisomer of 1,2-dimethylcyclopropane more stable than the other? wwwww
BUY
Chemistry
10th Edition
ISBN:
9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
expand_less
1 Chemical Foundations
2 Atoms, Molecules, And Ions
3 Stoichiometry
4 Types Of Chemical Reactions And Solution Stoichiometry
5 Gases
6 Thermochemistry
7 Atomic Structure And Periodicity
8 Bonding: General Concepts
9 Covalent Bonding: Orbitals
10 Liquids And Solids
11 Properties Of Solutions
12 Chemical Kinetics
13 Chemical Equilibrium
14 Acids And Bases
15 Acid-base Equilibria
16 Solubility And Complex Ion Equilibria
17 Spontaneity, Entropy, And Free Energy
18 Electrochemistry
19 The Nucleus: A Chemist's View
20 The Representative Elements
21 Transition Metals And Coordination Chemistry
22 Organic And Biological Molecules
expand_more
Chapter Questions
expand_more
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Problem 2RQ: Is the scientific method suitable for solving problems only in the sciences? Explain.
Problem 3RQ: Which of the following statements could be tested by quantitative measurement? a. Ty Cobb was a...
Problem 4RQ: For each of the following pieces of glassware, provide sample measurement and discuss the number of...
Problem 5RQ: A student performed an analysis of a sample for its calcium content and got the following results:...
Problem 6RQ: Compare and contrast the multiplication/division significant figure rule to the significant figure...
Problem 7RQ: Explain how density can be used as a conversion factor to convert the volume of an object to the...
Problem 8RQ: On which temperature scale (F, C. or K) docs 1 degree represent the smallest change in temperature?
Problem 9RQ: Distinguish between physical changes and chemical changes.
Problem 10RQ: Why is the separation of mixtures into pure or relatively pure substances so important when...
Problem 1ALQ: a. There are 365 days per year, 24 hours per day, 12 months per year, and 60 minutes per hour. Use...
Problem 2ALQ
Problem 3ALQ: When a marble is dropped into a beaker of water, it sinks to the bottom. Which of the following is...
Problem 4ALQ
Problem 5ALQ: You may have noticed that when water boils, you can see bubbles that rise to the surface of the...
Problem 6ALQ: If you place a glass rod over a burning candle, the glass appears to turn black. What is happening...
Problem 7ALQ: Which characteristics of a solid, a liquid, and a gas are exhibited by each of the following...
Problem 8ALQ: Sketch a magnified view (showing atoms/molecules) of each of the following and explain: a. a...
Problem 9ALQ: Paracelsus, a sixteenth-century alchemist and healer, adopted as his slogan: "The patients are your...
Problem 10ALQ: What is wrong with the following statement? "The results of the experiment do not agree with the...
Problem 11ALQ: Why is it incorrect to say that the results of a measurement were accurate but not precise?
Problem 14ALQ: You have a 1.0-cm3 sample of lead and a 1.0-cm3 sample of glass. You drop each in separate beakers...
Problem 15ALQ: Consider the addition of 15.4 to 28. What would a mathematician say the answer is? What would a...
Problem 16ALQ: Consider multiplying 26.2 by 16.43. What would a mathematician say the answer is? What would a...
Problem 17ALQ: True or false? For mathematical operation performed on two measurements, the number of significant...
Problem 18ALQ: Is there a difference between a homogeneous mixture of hydrogen and oxygen in a 2:1 ratio and a...
Problem 19Q: The difference between a law and a theory is the difference between what and why. Explain.
Problem 20Q: The scientific method is a dynamic process. What does this mean?
Problem 21Q: Explain the fundamental steps of the scientific method.
Problem 22Q
Problem 23Q: A measurement is a quantitative observation involving both a number and a unit. What is a...
Problem 24Q: To determine the volume of a cube, a student measured one of the dimensions of the cube several...
Problem 25Q: What are significant figures? Show how to indicate the number one thousand to 1 significant figure,...
Problem 26Q: A cold front moves through and the temperature drops by 20 degrees. In which temperature scale would...
Problem 28Q: In a multiple-step calculation, is it better to round off the numbers to the correct number of...
Problem 29Q: Is the density of a gaseous substance larger or smaller than the density of a liquid or a solid at...
Problem 30Q: Give four examples illustrating each of the following terms. a. homogeneous mixture b. heterogeneous...
Problem 31E: Which of the following are exact numbers? a. There are 100 cm in 1 m. b. One meter equals 1.094...
Problem 32E: Indicate the number of significant figures in each of the following: a. This book contains more than...
Problem 33E: How many significant figures are there in each of die following values? a. 6.07 1015 b. 0.003840 c....
Problem 34E: How many significant figures are in each of the following? a. 100 b. 102 c. 103 d. 100. e. 0.0048...
Problem 35E: Round off each of the following numbers to the indicated number of significant digits, and write the...
Problem 36E: Use exponential notation to express the number 385,500 to a. one significant figure. b. two...
Problem 37E: You have liquid in each graduated cylinder shown: You then add both samples to a beaker. How would...
Problem 38E: The beakers shown below have different precisions. a. Label the amount of water in each of the three...
Problem 39E: Evaluate each of the following, and write the answer to the appropriate number of significant...
Problem 40E: Perform the following mathematical operations, and express each result to the correct number of...
Problem 41E: Perform the following mathematical operations, and express the result to the correct number of...
Problem 42E: Perform the following mathematical operations, and express the result to the correct number of...
Problem 43E: Perform each of the following conversions. a. 8.43 cm to millimeters b. 2.41 102 cm to meters c....
Problem 44E: a. How many kilograms are in 1 teragram? b. How many nanometers are in 6.50 x 102 terameters? c. How...
Problem 45E: Perform the following unit conversions. a. Congratulations! You and your spouse are the proud...
Problem 46E: Perform the following unit conversions. a. 908 oz to kilograms b. 12.8 L to gallons c. 125 mL to...
Problem 47E: Use the following exact conversion factors to perform the stated calculations: 512 yd -= 1 rod 40...
Problem 48E: Although the preferred SI unit of area is the square meter, land is often measured in the metric...
Problem 49E: Precious metals and gems are measured in troy weights in the English system: 24 grains 1 pennyweight...
Problem 50E: Apothecaries (druggists) use the following set of measures in the English system: 20 grains ap = 1...
Problem 51E: For a pharmacist dispensing pills or capsules, it is often easier to weigh the medication to be...
Problem 52E: A children's pain relief elixir contains 80. mg acetaminophen per 0.50 teaspoon. The dosage...
Problem 53E: Science fiction often uses nautical analogies to describe space travel. If the starship U.S.S....
Problem 54E: The world record for the hundred meter dash is 9.58 s. What is the corresponding average speed in...
Problem 55E: You are driving 65 mi/h and take your eyes off the road for just a second. What distance (in feet)...
Problem 56E: You pass a road sign saying New York 112 km. If you drive at a constant speed of 65 mi/h, how long...
Problem 57E: The dosage for an antibiotic is prescribed at 8.0 mg per kilo-gram of body weight, taken twice daily...
Problem 58E: In recent years, there has been a large push for an increase in the use of renewable resources to...
Problem 59E
Problem 60E: Carbon monoxide (CO) detectors sound an alarm when peak levels of carbon monoxide reach 100 parts...
Problem 61E: Convert the following Fahrenheit temperatures to the Celsius and Kelvin scales. a. 459F, an...
Problem 62E: A thermometer gives a reading of 96.1F 0.2F. What is the temperature in C? What is the uncertainty?
Problem 63E: Convert the following Celsius temperatures to Kelvin and to Fahrenheit degrees. a. the temperature...
Problem 64E: Convert the following Kelvin temperatures to Celsius and Fahrenheit degrees. a. the temperature that...
Problem 65E: At what temperature is the temperature in degrees Fahrenheit equal to twice the temperature in...
Problem 66E: The average daytime temperatures on the earth and Jupiter are 72F and 313 K, respectively. Calculate...
Problem 67E: Use the figure below to answer the following questions. a. Derive the relationship between C and X....
Problem 68E: Ethylene glycol is the main component in automobile anti-freeze. To monitor the temperature of an...
Problem 69E: A material will float on the surface of a liquid if the material has a density less than that of the...
Problem 70E: One metal object is a cube with edges of 3.00 cm and a mass of 140.4 g. A second metal object is a...
Problem 71E: A star is estimated to have a mass of 2 1036 kg. Assuming it to be a sphere of average radius 7.0 ...
Problem 72E: A rectangular block has dimensions 2.9 cm 3.5 cm 10.0 cm. The mass of the block is 615.0 g. What...
Problem 73E: Diamonds are measured in carats, and 1 carat = 0.200 g. The density of diamond is 3.51 g/cm3. a....
Problem 74E: At room temperature the element bromine, Br2, is a liquid with a density of 3.12 g/cm3. Calculate...
Problem 75E: A sample containing 33.42 g of metal pellets is poured into a graduated cylinder initially...
Problem 76E: The density of pure silver is 10.5 g/cm3 at 20C. If 5.25 g of pure silver pellets is added to a...
Problem 77E: In e-ach of the following pairs, which has the greater mass? (See Table 1.5.) a. 1.0 kg of feathers...
Problem 78E: a. Calculate the mass of ethanol in 1.50 qt of ethanol. (See Table 1.5.) b. Calculate the mass of...
Problem 79E: In each of the following pairs, which has the greater volume? a. 1.0 kg of feathers or 1.0 kg of...
Problem 80E: Using Table 1.5, calculate the volume of 25.0 g of each of the following substances at 1 atm. a....
Problem 81E: The density of osmium (the densest metal) is 22.57 g/cm3. If a 1.00-kg rectangular block of osmium...
Problem 82E: A copper wire (density = 8.96 g/cm3) has a diameter of 0.25 mm. If a sample of this copper wire has...
Problem 83E: Match each description below with the following microscopic pictures. More than one picture may fit...
Problem 84E: Define the following terms: solid, liquid, gas, pure substance, element, compound, homogeneous...
Problem 85E: What is the difference between homogeneous and heterogeneous matter? Classify each of the following...
Problem 86E: Classify the following mixtures as homogeneous or heterogeneous. a. potting soil b. white wine c....
Problem 87E: Classify each of the following as a mixture or a pure substance. a. water b. blood c. the oceans d....
Problem 88E: Suppose a teaspoon of magnesium filings and a teaspoon of powdered sulfur are placed together in a...
Problem 89E: If a piece of hard, white blackboard chalk is heated strongly in a flame, the mass of the piece of...
Problem 90E: During a very cold winter, the temperature may remain below freezing for extended periods. However,...
Problem 91E: Classify the following as physical or chemical changes. a. Moth balls gradually vaporize in a...
Problem 92E: The properties of a mixture are typically averages of the properties of its components. The...
Problem 93AE: Two spherical objects have the same mass. One floats on water; the other sinks. Which object has the...
Problem 94AE: A 194-g sample of caffeine (C8H10N4O2) contains 6.02 1023 molecules of caffeine. If a typical...
Problem 95AE: Lipitor, a pharmaceutical drug that has been shown to lower bad cholesterol levels while raising...
Problem 96AE: In Shakespeares Richard III, the First Murderer says: Take that, and that! [Stabs Clarence] If that...
Problem 97AE
Problem 98AE: In the opening scenes of the movie Raiders of the Lost Ark, Indiana Jones tries to remove a gold...
Problem 99AE
Problem 100AE: The active ingredient of aspirin tablets is acetylsalicylic acid, which, has a density of 1.4 g/cm3....
Problem 101AE: This year, like many past years, you begin to feel very sleepy alter eating a large helping of...
Problem 102AE: Which of the following are chemical changes? Which are physical changes? a. the cutting of food b....
Problem 103AE: A person with high cholesterol has 250 mg of cholesterol per 100.0 mL of blood. If the total blood...
Problem 104AE
Problem 105AE: A column of liquid is found to expand linearly on heating. Assume the column rises 5.25 cm for a...
Problem 106AE: A 25.00-g sample of a solid is placed in a graduated cylinder, and then the cylinder is filled to...
Problem 107AE: For each of the following, decide which block is more dense; the orange block, the blue block, or it...
Problem 108AE: According to the Official Rules of Baseball, a baseball must have a circumference not more than 9.25...
Problem 109AE: The density of an irregularly shaped object was determined as follows. The mass of the object was...
Problem 110AE: The chemist in Example 1.14 did some further experiments. She found that the pipet used to measure...
Problem 111CWP: The longest river in the world is the Nile River with a length of 4145 mi. How long is the Nile in...
Problem 112CWP: Secretariat is known as the horse with the fastest run in the Kentucky Derby. If Secretariats record...
Problem 113CWP: The hottest temperature recorded in the United States is 134F in Greenland Ranch, CA. The melting...
Problem 114CWP
Problem 115CWP: Which of the following statements is(are) true? a. A spoonful of sugar is a mixture. b. Only...
Problem 116CWP: Which of the following describes a chemical property? a. The density of iron is 7.87 g/cm3. b. A...
Problem 117CP: A rule of thumb in designing experiments is to avoid using a result that is the small difference...
Problem 118CP: Draw a picture showing the markings (graduations) on glassware that would allow you to make each of...
Problem 119CP: Many times errors are expressed in terms of percentage. The percent error is die absolute value of...
Problem 120CP: A person weighed 15 pennies on a balance and recorded the following masses: 3.112 g 3.109 g 3.059 g...
Problem 121CP: On October 21, 1982, the Bureau of the Mint changed the composition of pennies (see Exercise 120)....
Problem 122CP: As part of a science project, you study traffic patterns in your city at an intersection in the...
Problem 123CP: Sterling silver is a solid solution of silver and copper. If a piece of a sterling silver necklace...
Problem 124CP: Make molecular-level (microscopic) drawings for each of the following. a. Show the differences...
Problem 125CP: Confronted with the box shown in the diagram, you wish to discover something about its internal...
format_list_bulleted
See similar textbooks
Related questions
Q: Keq = 2.94 %3D R II R
A: Concepts: in cyclohexane ring itself, there can be two conformers by the ring flipping and Both are…
Q: 1 ethel 2 isopropylcyclohexane Which one would be a most stable cis?
A: The isomers which are formed by the rotation of single bond is known as conformation isomerism.
Q: identical,
A: 3 pairs of compound are given and relation between them asked.
Q: 8. How many stereoisomers does the following constitution have? OH H₂C=HC -CH=CHCH₂CH3 9. Draw the…
A:
Q: Draw two cyclic constitutional isomers of cis-1,2-dibromocyclopentane with the same size ring.
A: Given -> Compound -> cis-1,2-dibromo cyclopentane Constitutional Isomers also known as…
Q: Explain the four stereoisomers of 2,3-dibromopentane ?
A: Compounds that differs in the spatial arrangement in space but do possess identical chemical formula…
Q: 4. a) Calculate the units of unsaturation for the formula C6H10O2. b) Draw a structure of C6H1002…
A: Double bond equivalence (DBE) for the given molecular formula can be calculated by using the…
Q: H_C=CHCH,CH,CH2CH3 A CH3CH₂CH₂ H B H CH3 CH3CH₂CH₂ V Which of the alkenes above is the least stable…
A: Answer:Stability of alkenes can be compared on the basis of number of , higher the value of , higher…
Q: Place the methyl group and hydrogen atom on the structures below to depict the conformation of cis-…
A: Here, we have to place the methyl group and hydrogen atom on the given structures to depict the…
Q: How many tetrahedral stereogenic centers does PGF2a contain? Draw its enantiomer. How many of its…
A: The structure of PGF2α is shown below,
Q: What Is the molecular formula of compound E?
A: Given : structure of molecule Tip : coun atoms
Q: Consider the following representation of 1,2-dimethylcyclobutane. CH3 CH3
A:
Q: 1 ethel 2 isopropylcyclohexane Which structure would be most stable cis?
A: Cis - Groups are on same side. Either above or below the plane. Trans- Groups are on opposite…
Q: the most stable conformation for 1 tert-butyl-3-methlyclohexane
A: Most stable conformation drawn considering the syn diaxial interaction, steric crowding, the size of…
Q: Part B: NH2
A: A question based on molecules that is to be accomplished.
Q: Is cis-1,3-dimethylcyclohexane (total energy - 12.5020 kcal/mol) or trans-1,3-dimethylcyclohexane…
A: Given is, cis-1,3-dimethylcyclohexane (total energy - 12.5020 kcal/mol) and…
Q: The chiral catalyst (R)-BINAP-Ru is used to hydrogenate alkenes to give alkanes . The products are…
A: Given reaction,
Q: to show the relative position of substituents in space. ndicate the enantiomeric or diastereomeric…
A: The question is based on the concept of stereochemistry. we have to draw enantiomer and…
Q: Áll of the following conformational models are representative of 2,3-dimethylpentane. Which of these…
A: To determine the configuration of chiral center Newman projection converts to Fischer projection.…
Q: ● Name the following heterocyclic compounds: (Two ways)
A: Given are heterocyclic compounds.Heterocyclic compounds are cyclic compounds that contain…
Q: Consider 1,2-dimethylcyclohexane.Q: Which isomer, cis or trans, is more stable and why?
A: The possible isomers of 1,2-dimethylcyclohexane is shown below,
Q: Which of the following is the least stable confromation of cyclohexane?
A: •Stability of conformer=> Stability of conformer is depends upon strain present. •More the strain…
Q: What is the conformation of the single bond between the double bonds? What is the stereochemistry of…
A:
Q: Compounds 1 and 2 were prepared, and the difference in their heats of combustion was found to be…
A: Given are organic compounds.The given conformations are lowest-energy conformations of given…
Question
Transcribed Image Text:
**Question:** Why is one stereoisomer of 1,2-dimethylcyclopropane more stable than the other? **Explanation:** The stability of different stereoisomers of 1,2-dimethylcyclopropane can be attributed to different factors: 1. **Steric Strain:** - The spatial arrangement of atoms or groups in a molecule can lead to crowding, known as steric strain. In cyclopropane, the three-membered ring restricts rotation, which can increase steric strain. 2. **Angle Strain:** - Cyclopropane rings are highly strained due to the smaller bond angles compared to a typical tetrahedral angle (109.5°). However, the distribution of substituents can affect the overall stability depending on how they relieve or exacerbate this angle strain. 3. **Torsional Strain:** - The relative positions of the substituents (cis or trans) can impact the torsional strain. The eclipsing interactions are minimized in the trans isomer, which could lead to greater stability than the cis isomer. 4. **Substituent Interactions:** - Trans isomers generally tend to be more stable due to reduced steric hindrance between the larger substituents, which is more prevalent in the cis configuration. Understanding these factors helps to clarify why certain isomers are favored over others in terms of stability.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
See solution
Check out a sample Q&A here
Step 1
VIEW
Step 2
VIEW
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images
See solution
Check out a sample Q&A here
Knowledge Booster
Similar questions
arrow_back_ios
arrow_forward_ios
On the following energy diagram, identify the energy level of the cyclohexane conformation shown in the box. Energy (kJ/mol) A) I B) II CLU ||| IV Conformations 2
arrow_forward
correct stereoisomer for the reaction
arrow_forward
Which one of the structures below is the most stable / lowest energy confor of the cis disubstituted-cyclohexane? %3D II IV OII O IV
arrow_forward
Which alkene below has the most stable carbon-carbon double bond? A B C D B 0 D A
arrow_forward
Rank the following cyclohexane isomers in order of stability (where the Most Stable Isomer = 1). If you believe multiple isomers have the same approximate overall energies indicate this by ranking them with the same number. Me. Me Me.* Me Me Me Me Me Ме,. Me Me* Me Ме, Me Me Me
arrow_forward
Cyclopentadiene H
arrow_forward
87. Subject :- Chemistry
arrow_forward
What are the relative energy levels of the three staggered conformations of 2,3-dimethylbutane when looking down the C2-C3 bond? Me Me H Me Me Me Me Me. Me Conformation: 191 1ක් පුදා H Me Me Me H H H A B C Me A is the highest energy conformation and C is the lowest (energy level of B is in between the two) O A and B are equal energy, and C is the highest energy conformation A and B are equal energy, and C is the lowest energy conformation C is the highest energy conformation and A is the lowest (energy level of B is in between the two) O B is the highest energy conformation and C is the lowest (energy level of A is in between the two)
arrow_forward
5. a-G a- Convert the following Newman projection into the bond line structural formula. Must use stereobonds to indicate the orientation of the groups. H3CO CN b- Draw the anti, gauche, and eclipsed conformations of the following molecule using Newman projection. H H H H c- i. Which cyclopropane molecule has the highest torsional strain? ii. Which cyclopropane molecule has the lowest torsional strain? C b a
arrow_forward
How many unique stereoisomers exist for 1,2,3,4,5-pentachlorocyclohexane?
arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
arrow_back_ios
arrow_forward_ios
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS