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- Which of the following is the strongest acid? BRCH2CO2H ICH2CO2H O CICH2CO2H O FCH2CO2HPregabalin, C3H17NO2 is used as a treatment of epilepsy and neuropathic pain. NH2 pK, = 4.2 %3D H. pK = HO, = 3.4 Select the equilibrium corresponding the to the pK, = 9.8 CgH18NO2 (aq) + H20 (I) C3H17NO2 (aq) + OH (aq) C3H16NO2 (aq) + H20 (1) CgH17NO2 (aq) + OH (aq) CgH17NO2 (aq) + H20 (1) C3H18NO2 *(aq) + OH (aq) C3H17NO2 (aq) + H20 (1) CgH16NO2 (aq)+ H30*(aq)a) b) C) HBr CH3CH₂OOCH₂CH3 1. Hg(OAc)2, H₂O 2. NaBH4 1) BH₂ / THF 2) H₂O2 NaOH (aq) cold
- 51. Which is NOT a valid resonance structure for the conjugate base of this molecule? (A) (C) OEt (C) :0: : OEt (+) HBr ROOR ü (B) OCH 3 (D) 52. What is the major product of this reaction sequence? o Mg ether (A) (B) :0: (D) H OEt OEt H OEt X CH31 LOH LOCH₁Complete the reaction map by matching A-E with the given choices. H2 H2 B E Pt Cla Na in lig NH3 он + но Match each item to a choice AWhat is the order of increasing acidity for the following compounds? (least acidic to most acidic) CH3CH₂CO₂H BrCH₂CH₂CO₂H CH3CH₂CH₂OH I II III O IV, II, I, III O I, II, IV, III III, IV, II, I III, I, II, IV CH3CHBrCO₂H IV
- Provide the required information for the reaction scheme below: OH Compound B Compound C OH Compound A CHO CH2OH CHO CH2OH Compound E Compound Db) Name the following molecule, excluding stereochemistry ОН .Cl 4-chloro-1- Rbhei-2- c) Provide the IUPAC name for the molecule shown here with correct stereochemistry: CH3 SH d) Rank the following in order of increasing basicity in the gas phase (least basic to most basic): N. NH2 NH2 NH2 D F CThioglycolic acid, HSCH2CO2H, a substance used in depilatory agents (hair removers) has pKa = 3.42. What is the percent dissociation of thioglycolic acid in a buffer solution at pH = 3.0?
- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Summarize the relationship between pKa and acid strength by completing the following sentences: a. The higher the pKa of an acid, the stronger or weaker the acid. b. The lower the pKa of an acid, the stronger or weaker the acid.Rank the following compounds in order of decreasing basicity ( N' NH NH C