Fundamentals Of Analytical Chemistry
9th Edition
ISBN: 9781285640686
Author: Skoog
Publisher: Cengage
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- Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq)+H2SO4(aq)+MnO2(s)Na2SO4(aq)+MnCl2(aq)+H2O(l)+Cl2(g) Balance this equation.arrow_forwardA solution contains both iron(II) and iron(III) ions. A sample Of the solution is titrated with 35.0 ml, of M KMnO4, which oxidizes Fe2+ to Fe3+. The permanganate ion is reduced to manganese(ll) ion. The equation for this reaction is MnO4(aq)+8 H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+ +4H2OAnother 50.00-mL sample of the solution is treated with zinc, which reduces all the Fe3+ to Fe2+. The equation for this reaction is 2Fe3+(aq)+Zn(s)2Fe2+(aq)+Zn2+(aq)The resulting solution is again titrated with 0.0280 M KMnO4; this time 48.0 ml, is required. What are the concentrations of Fe2+ and Fe3+ in the solution?arrow_forwardThe iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?arrow_forward
- Why is it important to give the states of the reactants and products when giving an equation for H?arrow_forwardA student tries to determine experimentally the molar mass of aspirin (HAsp). She takes 1.00 g of aspirin, dissolves it in water, and neutralizes it with 17.6 mL of 0.315 M KOH. The equation for the reaction is HAsp(aq)+OH(aq)Asp(aq)+H2OWhat is the molar mass of aspirin?arrow_forwardThe element carbon undergoes many inorganic reactions, as well as being the basis for the field of organic chemistry. Write balanced chemical equations for the reactions of carbon described below. l type='a'> Carbon burns in an excess of oxygen (for example. in the air) to produce carbon dioxide. If the supply of oxygen is limited, carbon will still burn but will produce carbon monoxide rather than carbon dioxide. molten lithium metal is treated with carbon, lithium car bide, Li2C2 , is produced. i>Iron(II) oxide reacts with carbon above temperatures of about 700 °C to produce carbon monoxide gas and molten elemental iron. i>Carbon reacts with fluorine gas at high temperatures to make carbon tetrafluoride.arrow_forward
- Gold metal will not dissolve in either concentrated nitric acid or concentrated hydrochloric acid It will dissolve, however, in aqua regia, a mixture of the two concentrated acids. The products of the reaction are the AuCl4 ion and gaseous NO. Write a balanced equation for the dissolution of gold in aqua regia.arrow_forwardssume a highly magnified view of a solution of HCI that allows you to “see” the HCl. Draw this magnified view. If you dropped in a piece of magnesium, the magnesium would disappear, and hydrogen gas would he released. Represent this change using symbols for the elements, and write the balanced equation.arrow_forwardComplete and balance the following acid-base equations: (a) A solution of HClO4 is added to a solution of LiOH. (b) Aqueous H2SO4 reacts with NaOH. (c) Ba(OH)2 reacts with HF gas.arrow_forward
- The equation for a reaction by which a solution of sodium carbonate may be standardized is 2HC7H5O2+Na2CO32NaC7H5O2+H2O+CO2. A student determines that 5.038g of HC7H5O2 uses 51.89mL of sodium carbonate solution in the titration. Find the molarity of the sodium carbonate.arrow_forwardWhich of the following species is being oxidized in this redox reaction? Zn(s)+Cu2+(aq)Zn2+(aq)+Cu(s) a.Zn(s) b.Cu2+(aq) c.Zn2+(aq) d.Cu(s)arrow_forward4.112 A metallurgical firm wishes to dispose of 1300 gallons of waste sulfuric acid whose molarity is 1.37 M. Before disposal, it will be reacted with calcium hydroxide (slaked lime), which costs $0.23 per pound. (a) Write the balanced chemical equation for this process. (b) Determine the cost that the firm will incur from this use of slaked lime.arrow_forward
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