
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
(a) Calculate the value of Kc for the reaction:
PCl5 (g) PCl3 (g) + Cl2 (g) ΔH = Positive
Given that when 8.4 mol of PCl5 (g) is mixed with 1.8 mol of PCl3 (g) and allowed to come to equilibrium in a 10 dm3container the amount of PCl5 (g) at equilibrium is 7.2 mol.
Kc =
(b) Explain the effect of the following changes below on the value of Kc:
- Increasing temperature
- Lowering the concentration of chlorine (Cl2)
- Addition of a catalyst
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by stepSolved in 2 steps with 2 images

Follow-up Questions
Read through expert solutions to related follow-up questions below.
Follow-up Question
i believe your ans for Kc is incorrect
with Kc = 0.05
![Examples of cal. Kc.
Calculate the value of Kc for the reacher.
PCLSS
= P C3(g) + Cl₂(g).
Given that when 8.4 mol of PCs (s) is mixed
with 1-8 mor of PCL3(g) & allowed to come
to equilibrium in a 10dm³ container the
amount of PC`s(s) at equilibrum is 7.2 mol.
PCL5
- PCI 3
ndes initially 8.4
84-102
7-2
nores@eqmail.
Full conc in
mol/dm³
7-2
10.
13.29
+ Cl₂.
1.8.
(²+1.8) 1.2.
3.0/10
1-2
10.
= 0-72
0.30.
012.
kc = [PC13 ] [C1₂] = [03][012]=K=00
[PCL5]
En = takes in
Ex = gives
+
out.
ma](https://content.bartleby.com/qna-images/question/824ec50a-9f05-4b47-b4de-079791e47d11/68c5e66e-4876-49a0-93c8-3ba008313654/47o8smj_thumbnail.jpeg)
Transcribed Image Text:Examples of cal. Kc.
Calculate the value of Kc for the reacher.
PCLSS
= P C3(g) + Cl₂(g).
Given that when 8.4 mol of PCs (s) is mixed
with 1-8 mor of PCL3(g) & allowed to come
to equilibrium in a 10dm³ container the
amount of PC`s(s) at equilibrum is 7.2 mol.
PCL5
- PCI 3
ndes initially 8.4
84-102
7-2
nores@eqmail.
Full conc in
mol/dm³
7-2
10.
13.29
+ Cl₂.
1.8.
(²+1.8) 1.2.
3.0/10
1-2
10.
= 0-72
0.30.
012.
kc = [PC13 ] [C1₂] = [03][012]=K=00
[PCL5]
En = takes in
Ex = gives
+
out.
ma
Solution
by Bartleby Expert
Follow-up Questions
Read through expert solutions to related follow-up questions below.
Follow-up Question
i believe your ans for Kc is incorrect
with Kc = 0.05
![Examples of cal. Kc.
Calculate the value of Kc for the reacher.
PCLSS
= P C3(g) + Cl₂(g).
Given that when 8.4 mol of PCs (s) is mixed
with 1-8 mor of PCL3(g) & allowed to come
to equilibrium in a 10dm³ container the
amount of PC`s(s) at equilibrum is 7.2 mol.
PCL5
- PCI 3
ndes initially 8.4
84-102
7-2
nores@eqmail.
Full conc in
mol/dm³
7-2
10.
13.29
+ Cl₂.
1.8.
(²+1.8) 1.2.
3.0/10
1-2
10.
= 0-72
0.30.
012.
kc = [PC13 ] [C1₂] = [03][012]=K=00
[PCL5]
En = takes in
Ex = gives
+
out.
ma](https://content.bartleby.com/qna-images/question/824ec50a-9f05-4b47-b4de-079791e47d11/68c5e66e-4876-49a0-93c8-3ba008313654/47o8smj_thumbnail.jpeg)
Transcribed Image Text:Examples of cal. Kc.
Calculate the value of Kc for the reacher.
PCLSS
= P C3(g) + Cl₂(g).
Given that when 8.4 mol of PCs (s) is mixed
with 1-8 mor of PCL3(g) & allowed to come
to equilibrium in a 10dm³ container the
amount of PC`s(s) at equilibrum is 7.2 mol.
PCL5
- PCI 3
ndes initially 8.4
84-102
7-2
nores@eqmail.
Full conc in
mol/dm³
7-2
10.
13.29
+ Cl₂.
1.8.
(²+1.8) 1.2.
3.0/10
1-2
10.
= 0-72
0.30.
012.
kc = [PC13 ] [C1₂] = [03][012]=K=00
[PCL5]
En = takes in
Ex = gives
+
out.
ma
Solution
by Bartleby Expert
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Calculate the value of K, for the equation C(s) + CO₂(g) given that at a certain temperature Kp = 2 CO(g) K₂ = ? C(s) + 2 H₂O(g) CO₂(g) + 2 H₂(g) H₂(g) + CO₂(g) = H₂O(g) + CO(g) Kpl = 3.35 Kp2 = 0.745arrow_forwardCalculate the value of K, for the equation C(s) + CO, (g) =2 CO(g) Kp = given that at a certain temperature C(s) + 2 H,O(g) = CO,(g) + 2 H,(g) Kp1 = = 3.51 H, (g) + CO, (g) =H,0(g)+CO(g) Kp2 = = 0.759 Kp = * TOOLS x10arrow_forwardWhat will happen to the equilibrium, NaHCO3(s)Na2CO3(s) + CO2(g) + H2O(g);Ho = 136 kJ when: (a) the temperature is decreased(b) the volume of the container is increased (c) water vapor is removed(d) additional Na2CO3 is added(e) pressure of CO2 is increasedarrow_forward
- For this equilibrium system, 2SO3(g) 2 25O2(g) + O2(g), Kc = 0.00407. At equilibrium, you would expect to find %3D relatively more products than reactant. relatively more reactant than products. about comparable amounts of reactant and products. no way to decide.arrow_forward2. According to Le Chatelier's principle, it indicates where the balance is favored (Reactants or products) of the following unbalanced reaction H₂O(a) + Fe(s) + H₂(g) + Fe3O4(s) + Heat Write your answer on the line a) Decreases ia [H2): b) The temperature of the system decreases: c) The system pressure increases:arrow_forwardKm.201.arrow_forward
- Consider the following reversible reaction at equilibrium: C6H12O6(aq) + 6 O2(g) 6 CO2(g) + 6 H2O(l). Given that this reaction is exothermic, if heat is added to the equilibrium system, how is the stress relieved?arrow_forward(a) Calculate K at 298 K for the following reaction: NO(g) + O₂(g) → NO₂(g) 1 2 K= = kJ AG (M) fmol 86.60 NO(g) NO₂(g) 51 O₂(g) 0 x 10arrow_forwardCalculate Kc for the following equilibrium: 2SO2(g) + O2(g) ⇌ 2SO3(g); Kp = 2.5 × 1010 at 4.5 × 102 K.arrow_forward
- Calculate the value of Kp for the equation C(s) + CO₂(g) 2 CO(g) given that at a certain temperature Kp Kp = ? C(s) + 2 H₂O(g)CO₂(g) + 2 H₂(g) H₂(g) + CO₂(g) H₂O(g) + CO(g) Kpl = 3.13 Kp2 = 0.625arrow_forwardAt -8.64 °C the concentration equilibrium constant K = 7.7 for a certain reaction. Here are some facts about the reaction: -1 • The initial rate of the reaction is 5.3 mol·L¯¹·s¯¹. . If the reaction is run at constant pressure, 132. kJ/mol of heat are absorbed. • The constant pressure molar heat capacity C = 2.97 J'mol K¹. Yes. Using these facts, can you calculate K at 16. °C? x10 O No. If you said yes, then enter your answer at right. Round it to 2 significant digits. If you said no, can you at least decide whether Kat 16. °C will be bigger or smaller than K at -8.64 °C? C Yes, and K will be bigger. Yes, and K will be smaller. No.arrow_forwardThe equilibrium constant for the following reaction is 67.6 at 232 °C. PCI 3(g) + Cl₂(g) PCI5(g) K = 67.6 at 232 °C Calculate the equilibrium constant for the following reactions at 232 °C. (a) PCI5(g) PCl3(g) + Cl₂(g) K= (b) 2 PCI5(g) 2 PCI3(g) + 2 Cl₂(g) K=arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY