When 30 mL of 1.0 M HCl was mixed with 50 mL of 1.0 M NaOH in a coffee cup calorimeter, the temperature of the solution rose from 24.8 C to 41.5 C.  Determine the heat of the reaction.  Is the reaction endothermic or exothermic? Explain.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter5: Principles Of Chemical Reactivity: Energy And Chemical Reactions
Section5.6: Calorimetry
Problem 5.7CYU: Assume 200. mL of 0.400 M HCl is mixed with 200. mL of 0.400 M NaOH in a coffee-cup calorimeter The...
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When 30 mL of 1.0 M HCl was mixed with 50 mL of 1.0 M NaOH in a coffee cup calorimeter, the temperature of the solution rose from 24.8 C to 41.5 C.  Determine the heat of the reaction.  Is the reaction endothermic or exothermic? Explain.

Expert Solution
Step 1

Recall the following relation to calculate amount of heat(Q) gained by water

        Q=m×C×tHere,mass of solutionm=30 mL×1 g1 mL +50 mL×1 g1 mL                                     =80 g       Specific heat capacity of water(C)=4.184 J/g°C       Change in temperaturet=41.5°C-24.8°C                                               =16.7°C30 mL 1.0 M HCl and 50 mL 1.0 M NaOH are mixed.We have to find Hrxn° for the reaction that will occur.

 

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