Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
Bartleby Related Questions Icon

Related questions

bartleby

Concept explainers

Question
What would be the correct structure based on the following NMR data Molecule formula: C8H8O2 - S:3.6ppm. Singlet,3H - S:7.4ppm and 7.8 ppm doublet of doublets 4H total -S:9.8ppm singlet,1H
Typical 'H Chemical Shifts
Type of Proton
Structure
Chemical Shift (ppm)
Alkyl groups
R3C-H
0.9 - 1.5
Vinyl (alkene)
C=C-H
4.6 – 5.9
Acetylene
C=C-H
2 - 3
Aromatic
Ar-H
6 - 8.5
Benzyl
Ar-C-H
2.2 - 3
Allyl and propargyl
C=C-CH3
1.7 – 2.5
Halides
Н-С-Х
2 - 4.5
Oxygen adjacent carbons
Н-С-ОН
3.4 - 4
Carbonyl adjacent carbons
H-C-COOR
1.9 – 2.7
Aldehyde hydrogen
R-CHO
9 - 10
Hydroxyl group
R-C-ОH
1- 5.5
Amino group
RNH2
1-5.5
Carboxylic acid hydrogen
Amides
RCOOH
10.5 -12
RNHCOR'
5-8.5
H-C-NO2
4.3 - 5.3
Nitro
expand button
Transcribed Image Text:Typical 'H Chemical Shifts Type of Proton Structure Chemical Shift (ppm) Alkyl groups R3C-H 0.9 - 1.5 Vinyl (alkene) C=C-H 4.6 – 5.9 Acetylene C=C-H 2 - 3 Aromatic Ar-H 6 - 8.5 Benzyl Ar-C-H 2.2 - 3 Allyl and propargyl C=C-CH3 1.7 – 2.5 Halides Н-С-Х 2 - 4.5 Oxygen adjacent carbons Н-С-ОН 3.4 - 4 Carbonyl adjacent carbons H-C-COOR 1.9 – 2.7 Aldehyde hydrogen R-CHO 9 - 10 Hydroxyl group R-C-ОH 1- 5.5 Amino group RNH2 1-5.5 Carboxylic acid hydrogen Amides RCOOH 10.5 -12 RNHCOR' 5-8.5 H-C-NO2 4.3 - 5.3 Nitro
Expert Solution
Check Mark
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY