Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
What is the total change in entropy of the universe (system + surroundings) if 3.5 g of CO(g) reacts completely with O2(g) to form CO2(g) under standard conditions (25 C, 1.0 bar, ideal gases)?
Include 3 significant figures
The answer is NOT:215.76 or 217.015
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- The heat of vaporization AH, of heptane (C-H16) is 31.2 kJ/mol. Calculate the change in entropy AS when 83. g of heptane boils at 98.4 °C. Be sure your answer contains a unit symbol. Round your answer to 2 significant digits. ☐ x10 μ ✓ Garrow_forwardCalculate the entropy change in surroundings when 1.00 mol of H:0 (1) is formed under standard conditions, A:H = -286 kJmol1. Industrially, methanol is synthesized using the reaction Co(e) + 2 H2(g) =CH:OH(g) Calculate the equilibrium constant at 298 K. AGP CO(g) = -137.2 kJ/mol; AGP H: (g)= 0; AGP CH:OH(g) = -162 kJ/molarrow_forward(Q68) Using the tabulated values from the text (located in Appendix G, beginning at p. 1211) calculate (and report in J/K) the standard entropy of reaction (AS°rxn) for the formation of gaseous nitric acid from its elements as indicated in the following balanced chemical equation: H2 (g) + N2 (g) + 3 O2 (g) --> 2 HNO3 (g)arrow_forward
- Please don't provide handwriting solutions....arrow_forwardRound everthing to 4 decimal places. Ammonia and carbon dioxide are produced from the hydrolysis of urea, the corresponding chemical reaction shown below:arrow_forwardThe energy produced by a spontaneous reaction is often used to provide the energy to drive nonspontaneous reactions. For example, the conversion of ATP to ADP in our cells acts as the energy source for the nonspontaneous reactions that combine amino acids during protein synthesis. Here is the conversion of ATP to ADP: ATP(aq) + H,O = ADP(aq) + HPO,²-(aq) AG° = -30.0 kj/mol A typical reaction combining two amino acids during protein synthesis has a AG = 15.0 kJ/mol. What is the minimum ATP concentration required to provide the energy to combine 1 mole of amino acid synthesis (total energy = 15.0 kJ)? Assume that the concentration of ADP = 9 µM (micromolar) and HPO42- = 4 mM (millimolar). %3! %3Darrow_forward
- For the following reaction (the detonation of nitroglycerin), is it spontaneous under standard conditions and how can you tell? 4 C4H5N3O9(l) (arrow >) 12 CO2(g) + 10 H2O(g) + 6 N2(g) + O2(g) ΔH = -5678 kJarrow_forward0/5 Nerbs A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 85.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. do AH = -2220. kJ J AS = -6189 K C,H, (g) + 50, (g) 3Co, (g) + 4H,0(1) AG = KJ Which is spontaneous? O this reaction O the reverse reaction O neither AH = -50. kJ 0- AS =…arrow_forwardVhemical engineer is studying the two'reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 82.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2NH, (g) N₂(g)+ 3H₂ (e) 2A1(s) + Fe₂O₂ (s) ALO, (s) + 2Fe(s) AH = 92, kJ AS = 302. FR AG = KJ Which is spontaneous? Othis reaction AS = the reverse reaction Oneither AH = -852. kJ K AG…arrow_forward
- AG (ky/mol) SUbStance / 1on so (ky/mol) -1206.9 /moi k) 92.9 • CaC03l>) -|128.8 • CaO (s) |- 635. I – 60 3.5 38.2 • CO2(9) - 393.5 - 394.4 213.7 191.5 3 H2(g) 202.7 ZNH3 ) -45.9 -16 193 • Hz (g) 202.7 223.0 -92.31 - 95. 30 186.79arrow_forwardM Preq 3 Consider the reaction 00 E D 4HCI(g) + O₂(g) 2H₂O(g) + 2Cl₂(8) for which AH° = -114.4 kJ and AS° = -128.9 J/K at 298.15 K. J/K (1) Calculate the entropy change of the UNIVERSE when 1.775 moles of HCI(g) react under standard conditions at 298.15 K. ASuniverse (2) Is this reaction reactant or product favored under standard conditions? Submit Answer (3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored choose 'reactant favored'. 4 000 000 R F DO LO V % 5 [Review Topics] [References] Use the References to access important values if needed for this question. T Retry Entire Group 8 more group attempts remaining Cengage Learning Cengage Technical Support G 6 B Y H & 7 N U 1 * 8 J M 9 K बैं O < L P Previous Email Instructor Save and Exit { + 11 Next ? } ]arrow_forwardExplain pleaseeeeeeeeeeearrow_forward
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