Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Consider the reactionCa(OH)2(aq) + 2HCl(aq)CaCl2(s) + 2H2O(l)for which H° = -30.20 kJ and S° = 205.9 J/K at 298.15 K.(1) Calculate the entropy change of the UNIVERSE when 2.325 moles of Ca(OH)2(aq) react under standard conditions at 298.15 K.Suniverse = J/K(2) Is this reaction reactant or product favored under standard conditions?(3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored, choose 'reactant favored'.arrow_forwardConsider the reactionS(s,rhombic) + 2CO(g)SO2(g) + 2C(s,graphite)for which H° = -75.80 kJ and S° = -167.6 J/K at 298.15 K.(1) Calculate the entropy change of the UNIVERSE when 1.716 moles of S(s,rhombic) react under standard conditions at 298.15 K. Suniverse = J/K (2) Is this reaction reactant or product favored under standard conditions?(3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored choose 'reactant favored'.arrow_forwardConsider the reaction 2NaOH(aq) + H2(g)—2Na(s) + 2H2O(l) for which AH° = 368.6 kJ and AS° = 15.30 J/K at 298.15 K. (1) Calculate the entropy change of the UNIVERSE when 1.759 moles of NaOH(aq) react under standard conditions at 298.15 K. ASuniverse= J/K (2) Is this reaction reactant or product favored under standard conditions? (3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored, choose 'reactant favored'. Submit Answerarrow_forward
- For the following reaction (the detonation of nitroglycerin), is it spontaneous under standard conditions and how can you tell? 4 C4H5N3O9(l) (arrow >) 12 CO2(g) + 10 H2O(g) + 6 N2(g) + O2(g) ΔH = -5678 kJarrow_forwardConsider the reaction 6CO2(g) + 6H20((1) C,H12O6 + 602(g) for which AH° = 2.801×10° kJ and AS° = -259.0 J/K at 298.15 K. (1) Calculate the entropy change of the UNIVERSE when 1.722 moles of CO2(g) react under standard conditions at 298.15 K. ASuniverse J/K (2) Is this reaction reactant or product favored under standard conditions? (3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored, choose 'reactant favored'.arrow_forwardThe decomposition of copper (1) oxide to its elements does not occur spontaneously at 375°C (AG = 140.0 kJ): Cu₂0 (s) 2 Cu (s) + 1/2O₂(g). It can be made to occur spontaneously by being coupled to the oxidation of solid carbon to form carbon monoxide gas at this same temperature (AG = -143.8 kJ): C(s) + 1/2O₂(g) → CO (g) What product(s) is/are produced as a result of coupling the two reactions? CO (g) 2 Cu (s) and 1/2 O₂ (g) 2 Cu (s) and CO (g) 2 Cu (s), 1/2 O2 (g), and CO (g) 1/2 0₂ (g)arrow_forward
- Consider the reaction Fe(s) + 2HCl(aq) → FeCl₂ (s) + H₂(g) for which AH = -7.400 kJ and AS = 107.9 J/K at 298.15 K. 1. Calculate the entropy change of the UNIVERSE when 2.385 moles of Fe(s) react under standard conditions at 298.15 K. ASuniverse J/K 2. Is this reaction reactant or product favored under standard conditions? 3. If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored, choose 'reactant favored'. Submit Answer Retry Entire Group 5 more group attempts remainingarrow_forwardCalculate AGran in kJ, at 298K for the following reaction using the conditions given below. R = 8.314 J/mol.K SO3 (g) + H₂O (9) H₂SO4 (1) AGran = -90.5 (A) mol Pso3 = 0.20 atm, Pu,o = 0.88 atm Express your answer to one decimal place.arrow_forward"M" represents a metallic element. "X" represents a nonmetallic element. Calculate ΔH for the process M3X4(s) ⟶ 3M(s) + 2X2(g) from the following information: M(s) + ½X2(g) ⟶ MX(s) ΔH°= -286.2 kJ 3MX(s) + ½X2(g) ⟶ M3X4(s) ΔH°= -84.3 kJarrow_forward
- M Preq 3 Consider the reaction 00 E D 4HCI(g) + O₂(g) 2H₂O(g) + 2Cl₂(8) for which AH° = -114.4 kJ and AS° = -128.9 J/K at 298.15 K. J/K (1) Calculate the entropy change of the UNIVERSE when 1.775 moles of HCI(g) react under standard conditions at 298.15 K. ASuniverse (2) Is this reaction reactant or product favored under standard conditions? Submit Answer (3) If the reaction is product favored, is it enthalpy favored, entropy favored, or favored by both enthalpy and entropy? If the reaction is reactant favored choose 'reactant favored'. 4 000 000 R F DO LO V % 5 [Review Topics] [References] Use the References to access important values if needed for this question. T Retry Entire Group 8 more group attempts remaining Cengage Learning Cengage Technical Support G 6 B Y H & 7 N U 1 * 8 J M 9 K बैं O < L P Previous Email Instructor Save and Exit { + 11 Next ? } ]arrow_forwardO-234 kJ 234 kJ -150. kJ -117 kJ Given: -1835kJ AH°, AHᵒf (kJ/mol) -941 -840 QUESTION 12 Use the standard reaction enthalpies given below to determine AH°rxn for the following reaction: P4(g) + 10 Cl₂(g) → 4 PC|5(s) PC15(s) → PC13(g) + Cl₂(g) P4(g) + 6 Cl₂(g) → 4 PCl3(g) rxn IF7(g) IF 5(9) 2(g) 62.42 = ? ΔΗ° rxn AH°rxn = +157 kJ = -1207 KJ QUESTION 13 Use the AH°f and AH°rxn information provided to calculate AH°f for IF: IF7(9) + 12(g) → IF5(g) + 2 IF(g) AH°rxn = -89 kJarrow_forwardFor the reaction C(s,graphite) + 02(g) CO2(g) AG° = -394.3 kJ and AS° = 2.9 J/K at 290 K and 1 atm. This reaction is (reactant, product) favored under standard conditions at 290 K. The standard enthalpy change for the reaction of 2.38 moles of C(s,graphite) at this temperature would be kJ.arrow_forward
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