
Chemistry
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Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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What diene and dienophile are used in Dies-Alder route to the compound shown?

Transcribed Image Text:Part A
What diene and dienophile are used in the Diels-Alder
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- Current Attempt in Progress Rank the following dienophiles (from least reactive to most reactive) in terms of reactivity in a Diels-Alder reaction. A Compound Compound B is the LEAST reactive dienophile, because it has is the MOST reactive dienophile, because it has no electron-withdrawing groups two electron-withdrawing groups one electron-withdrawing grouparrow_forwardProblem 8. Provide a mechanism. Hint: remember the Swern oxidation Me. BF4 DMSO, K₂CO3 Me. Harrow_forward15. Label the following transition state with the applicable following items (not all labels will apply) i. HOMO of the diene LUMO of the diene HOMO of the dienophile LUMO of the dienophile v. Constructive overlap vi. Destructive overlap II. III. iv. /H₂SQ? +arrow_forward
- 16.7 Diels-Alder Reactions Predict the major product of the following reaction. + heat ?arrow_forwardWhy does the diene need to be in the s-cis conformation to yield the cyclic product?arrow_forward24) Place the best reagent and conditions in the bins for each of the following reactions (stereochemistry is omitted) NH3 CrO3, H3O+ OH NH₂ 1. 2. OH SOCI2 CH3MgBr NaN3 CH3NH2 NaCl 1. 2. CH3CO₂Na CH3ONa CH3CH₂OH iPrMgBr NaBH4 CH3OH H3O+ OH oh LIAIH4arrow_forward
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