
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Use the Trouton's rule to estimate the normal enthalpy of vaporization of a material that boil at 147 oC and 1 atm. ΔvapH = __________ kJ/mol, 3 sig. fig. double check sign and unit.
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Introduction
The Troutons rule is an empirical relation relating the enthalpy of vaporisation and boiling temperature. According to this rule “the entropy of vaporization is almost the same value, about 85–88 J /K/mol for various kinds of liquids at their boiling points.” The entropy of vaporization is expressed as the ratio between the enthalpy of vaporization and the boiling temperature.
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- Calculate the enthalpy of vaporization of acetamide given the following data table. Vapor Pressure (kPa) Temperature ("C) 1.000 102.8 10.000 150.8 100.000 218.2arrow_forwardThe vapor pressure, P, of a certain liquid was measured at two temperatures, T. The data is shown in the table. ТК) Р (КРа) 225 3.40 725 7.58 Keep the pressure units in kilopascals. If you were going to graphically determine the enthalpy of vaporizaton, AHvap, for this liquid, what points would you plot? To avoid rounding errors, use three significant figures in the x-values and four significant figures in the y-values. point 1: x = point 1: y = TOOLS x10 point 2: x = point 2: y = Determine the rise, run, and slope of the line formed by these points. rise = run = slope =arrow_forwardANS B ONLY a. The molar volume of a certain solid is 142.0 cm3 mol−1 at 1.00 atm and 427.15 K, its melting temperature. The molar volume of the liquid at this temperature and pressure is 152.6 cm3 mol−1. At 1.2 MPa the melting temperature changes to 429.26 K. Calculate the enthalpy (KJ/mol) and entropy of fusion (J/mol-K) of the solid. b. Calculate the melting point of ice under a pressure of 10 MPa. Assume that the density of ice under these conditions is approximately 0.915 g cm−3 and that of liquid water is 0.998 g cm−3. From the result of the calculation, what happens when you increase the pressure on water, will it freeze or will the ice melt?arrow_forward
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