Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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a. The molar volume of a certain solid is 142.0 cm3 mol−1 at 1.00 atm and 427.15 K, its melting temperature. The molar volume of the liquid at this temperature and pressure is 152.6 cm3 mol−1.  At 1.2 MPa the melting temperature changes to 429.26 K. Calculate the enthalpy (KJ/mol) and entropy of fusion (J/mol-K) of the solid.

b. Calculate the melting point of ice under a pressure of 10 MPa. Assume that the density of ice under these conditions is approximately 0.915 g cm−3 and that of liquid water is 0.998 g cm−3. From the result of the calculation, what happens when you increase the pressure on water, will it freeze or will the ice melt?

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