Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Using Graham's Law of Effusion to Calculate Molar Mass**

A sample of **krypton**, Kr, effuses through a small hole at a rate of \(9.00 \times 10^{-6}\) mol/h. An unknown gas, under the same conditions, effuses at a rate of \(1.93 \times 10^{-5}\) mol/h. Calculate the molar mass of the unknown gas.

\[ \_\_\_\_\_\_ \text{ g/mol} \]

(Note: In order to find the molar mass of the unknown gas, you can apply Graham's Law of Effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. The formula is \(\frac{\text{Rate}_1}{\text{Rate}_2} = \sqrt{\frac{M_2}{M_1}}\), where \(\text{Rate}_1\) and \(\text{Rate}_2\) are the effusion rates of the gases, and \(M_1\) and \(M_2\) are their molar masses.)
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Transcribed Image Text:**Using Graham's Law of Effusion to Calculate Molar Mass** A sample of **krypton**, Kr, effuses through a small hole at a rate of \(9.00 \times 10^{-6}\) mol/h. An unknown gas, under the same conditions, effuses at a rate of \(1.93 \times 10^{-5}\) mol/h. Calculate the molar mass of the unknown gas. \[ \_\_\_\_\_\_ \text{ g/mol} \] (Note: In order to find the molar mass of the unknown gas, you can apply Graham's Law of Effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. The formula is \(\frac{\text{Rate}_1}{\text{Rate}_2} = \sqrt{\frac{M_2}{M_1}}\), where \(\text{Rate}_1\) and \(\text{Rate}_2\) are the effusion rates of the gases, and \(M_1\) and \(M_2\) are their molar masses.)
**Calculate Pressure Using the Ideal Gas Law and the van der Waals Equation**

A 1.88-mol sample of argon gas is maintained in a 0.608-L container at 297 K. Calculate the pressure of the gas using both the ideal gas law and the van der Waals equation (van der Waals constants for Ar are \( a = 1.35 \, \text{L}^2\text{atm/mol}^2 \) and \( b = 3.22 \times 10^{-2} \, \text{L/mol} \)).

\[ P_{\text{ideal gas equation}} = \_\_\_\_ \, \text{atm} \]

\[ P_{\text{van der Waals}} = \_\_\_\_ \, \text{atm} \]
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Transcribed Image Text:**Calculate Pressure Using the Ideal Gas Law and the van der Waals Equation** A 1.88-mol sample of argon gas is maintained in a 0.608-L container at 297 K. Calculate the pressure of the gas using both the ideal gas law and the van der Waals equation (van der Waals constants for Ar are \( a = 1.35 \, \text{L}^2\text{atm/mol}^2 \) and \( b = 3.22 \times 10^{-2} \, \text{L/mol} \)). \[ P_{\text{ideal gas equation}} = \_\_\_\_ \, \text{atm} \] \[ P_{\text{van der Waals}} = \_\_\_\_ \, \text{atm} \]
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