Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- - 1 Under certain conditions the rate of this reaction is zero order in ammonia with a rate constant of 0.0038 M's : 2 NH3 (g) - → N, (g) + 3 H2 (g) Suppose a 450. mL flask is charged under these conditions with 350. mmol of ammonia. How much is left 50. s later? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.arrow_forward2. Consider the reaction that occurs when a CIO2 solution and a solution containing hydroxide ions (OH) are mixed at 0°C, shown in the following equation. 2CIO2(aq) + 2OH (aq) → Cl03° (aq) + CIO2° (aq) + H2O (1) When solutions containing CIO2 and OH- in various concentrations were mixed at 0 oC, the following rate data were obtained: Determination Initial concentration Initial concentration of Initial rate for formation number of ClO2, mol/L OH", mol/L of CIO3¯ mol/Ls 1.25x10-2 1.30x10-3 2.33x10-4 2.50x10-2 1.30x10-3 9.34x104 3 2.50x10-2 2.60x103 1.87x10-3 a) Use the method of initial rates to find the order of the reaction with respect to CIO2 and with respect to OH. Write the rate equation for the reaction of CIO2 and OH´ at 0°C. b) Calculate the rate constant, k, for the reaction of clO2 and OH at 0°C. c) Calculate the reaction rate for the reaction CIO2 and OH at 0°C when the initial ClO2 and OH concentrations are 8.25x10-3 mol/L and 5.35x 10-² mol/L, respectively. 1.arrow_forwardUnder certain conditions the rate of this reaction is zero order in dinitrogen monoxide with a rate constant of 0.0022 Ms: 2N,0 (g) - 2N, (g) +0, (g) Suppose a 400. mL flask is charged under these conditions with 500. mmol of dinitrogen monoxide. After how much time is there only 250. mmol left? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits. 10 Ararrow_forward
- Consider the following reaction: 4 NH_{3} + 5 O_{2} → 4 NO + 6 H_{2}O The rate of consumption of NH_3 is -1.4×10^{-5} M/s. Calculate the relative reaction rate. Use “E” for scientific notation. Do not enter units as part of your answer.arrow_forwardA zero order reaction has a constant rate of 3.1 × 10−4 mol·L−1·s−1. If after 60 seconds the concentration has dropped to 4.7 × 10−2 mol·L−1, what was the initial concentration (in mol·L−1)? Express your answer to two significant figures.arrow_forwardUnder certain conditions the rate of this reaction is zero order in hydrogen iodide with a rate constant of 0.0041 M's : 2 HI(g) → H2(g)+I,(g) Suppose a 4.0 L flask is charged under these conditions with 300. mmol of hydrogen iodide. After how much time is there only 150. mmol left? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. x10arrow_forward
- - 1 Under certain conditions the rate of this reaction is zero order in hydrogen iodide with a rate constant of 0.0020 M·s 2 HI (g) → H, (g) + I, (g) Suppose a 4.0 L flask is charged under these conditions with 150. mmol of hydrogen iodide. How much is left 5.0 s later? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.arrow_forwardUnder certain conditions the rate of this reaction is zero order in hydrogen iodide with a rate constant of 0.0044 M's : 2 HI (g) - H, (g) +I, (g) Suppose a 3.0 L flask is charged under these conditions with 400. mmol of hydrogen iodide. How much is left 8.0 s later? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. x10arrow_forward5. You studied the chemical reaction, 2NO2(g) → 2NO(g) + O2(g), at 25°C by monitoring the concentration of NO2(g) as a function of time and constructed the following graph. y= 0.5408x + 125.0 R2=0.998 Time (s) What is the rate constant for this reaction at 25°C? Include the proper units. (W/T) [(3)ONI/Tarrow_forward
- Consider this reaction: 2SO3 (g) →2SO₂(g) + O₂(g) At a certain temperature it obeys this rate law. rate = (0.894 M¹-s¹) [S0₂] Suppose a vessel contains SO3 at a concentration of 0.390 M. Calculate the concentration of SO3 in the vessel 8.60 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits. M Explanation Check 0 10 Q Search a Ⓒ2023 McGraw Hill LLC. All Rights Reserved. Terms of Use O Privacy Centerarrow_forwardIn the reaction 2HgO → 2 Hg + O2 the evolution of gas is used to determine the rate of reaction. At the beginning of the reaction, 0.02 L of O2 is present. After 15 minutes the volume of gas is 0.35 L. What is the rate of reaction in liters/min?arrow_forwardConsider this reaction: 2HI (g) → H, (g) +I, (g) At a certain temperature it obeys this rate law. rate =(0,465 s)[HI Suppose a vessel contains HI at a concentration of 0.540M. Calculate the concentration of HI in the vessel 2.80 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits.arrow_forward
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